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We measure primary drainage capillary pressure and the relationship between initial and residual non‐wetting phase saturation for a supercritical carbon dioxide (CO2)‐brine system in Berea sandstone. We use the semi‐permeable disk (porous‐plate) coreflood method. Brine and CO2 were equilibrated prior to injection to ensure immiscible displacement. A maximum CO2 saturation of 85% was measured for an applied capillary pressure of 296 kPa. After injection of brine the CO2 saturation dropped to 35%; this is less than the maximum trapped saturation of 48% measured in an equivalent n‐decane (oil)‐brine experiment. The dimensionless capillary pressure is the same to within experimental error for supercritical CO2‐brine, n‐decane‐brine and a mercury‐air system. CO2 is the non‐wetting phase and significant quantities can be trapped by capillary forces. We discuss the implications for CO2 storage.
Geophysical Research Letters – Wiley
Published: Mar 1, 2011
Keywords: ; ; ; ;
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