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The probability of a configuration is given in classical theory by the Boltzmann formula exp ( - V hT ) where V is the potential energy of this configuration. For high temperatures this of course also holds in quantum theory. For lower temperatures, however, a correction term has to be introduced, which can be developed into a power series of h . The formula is developed for this correction by means of a probability function and the result discussed.
Physical Review – American Physical Society (APS)
Published: Jun 1, 1932
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