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Blauwhoff Blauwhoff, Kamphuis Kamphuis, van Swaaij van Swaaij, Westerterp Westerterp (1985)
Absorber Design in Sour Natural Gas Treatment Plants: Impact of Process Variables on Operation and EconomicsChem. Eng. Proc., 19
E. Sada, H. Kumazawa, Y. Ikehara, Z. Han (1989)
Chemical kinetics of the reaction of carbon dioxide with triethanolamine in non-aqueous solventsChemical Engineering Journal, 40
P. Blauwhoff, G. Versteeg, W. Swaaij (1983)
A study on the reaction between CO2 and alkanolamines in aqueous solutionsChemical Engineering Science, 38
(1989)
Selective H , S Removal by Mixed Solvents
G. Versteeg, P. Blauwhoff, W. Swaaij (1987)
The effect of diffusivity on gas-liquid mass transfer in stirred vessels. Experiments at atmospheric and elevated pressuresChemical Engineering Science, 42
Versteeg Versteeg, Kuipers Kuipers, van Beckum van Beckum, van Swaaij van Swaaij (1989)
Mass Transfer with Complex Reversible Chemical Reactions: I. Single Reversible Chemical ReactionsChem. Eng. Sci., 44
H. Hikita, S. Asai, H. Ishikawa, M. Honda (1977)
The kinetics of reactions of carbon dioxide with monoisopropanolamine, diglycolamine and ethylenediamine by a rapid mixing methodChemical Engineering Journal, 14
Giovanni Astarita (1967)
Mass Transfer With Chemical Reaction
(1985)
Tomcej and Otto (1989), and the reinterpreted data of Versteeg and Van Swaaij (1988b). DMMEA-H,O
E. Sada, H. Kumazawa, M. Butt (1976)
Gas absorption with consecutive chemical reaction: Absorption of carbon dioxide into aqueous amine solutionsCanadian Journal of Chemical Engineering, 54
D. Glasscock, G. Rochelle (1989)
Numerical simulation of theories for gas absorption with chemical reactionAiche Journal, 35
S. Laddha, J. Díaz, P. Danckwerts (1981)
The N2O analogy: The solubilities of CO2 and N2O in aqueous solutions of organic compoundsChemical Engineering Science, 36
Wei Yu, G. Astarita, D. Savage (1985)
Kinetics of carbon dioxide absorption in solutions of methyldiethanolamineChemical Engineering Science, 40
Donaldson Donaldson, Nguyen Nguyen (1980)
Carbon Dioxide Reaction and Transportation in Aqueous Amine MembranesInd. Eng. Chem. Fundam., 19
P.M.M Blauwhoff, B. Kamphuis, W.P.M Swaaij, K. Westerterp (1985)
Absorber design in sour natural gas treatment plants: Impact of process variables on operation and economics = Absorberentwurf für Anlagen zur Behandlung von sauren Erdgasen: Einfluss Prozessparameter auf Betriebsführung und ProzesswirtschaftlichkeitChemical Engineering and Processing, 19
Versteeg Versteeg, van Swaaij van Swaaij (1988a)
On the Kinetics between CO 2 and Alkanolamines both in Aqueous and Nonaqueous Solutions: I. Primary and Secondary AminesChem. Eng. Sci., 43
Versteeg Versteeg, van Swaaij van Swaaij (1988b)
On the Kinetics between CO 2 and Alkanolamines both in Aqueous and Nonaqueous Solutions: II. Tertiary AminesChem. Eng. Sci., 43
R. Littel, M. Bos, Gerdine Knoop (1990)
Dissociation constants of some alkanolamines at 293, 303, 318, and 333 KJournal of Chemical & Engineering Data, 35
J. Crooks, J. Donnellan (1990)
Kinetics of the reaction between carbon dioxide and tertiary aminesJournal of Organic Chemistry, 55
C. Kim, D. Savage (1987)
Kinetics of carbon dioxide reaction with diethylaminoethanol in aqueous solutionsChemical Engineering Science, 42
(1965)
Moniuk, “Kinetics of Reaction between Carbon
Hikita Hikita, Asai Asai, Ishikawa Ishikawa, Honda Honda (1977)
The Kinetics of the Reaction of Carbon Dioxide with Monoethanolamine, Diethanolamine and Triethanolamine by a Rapid Mixing MethodChem. Eng. J., 13
Versteeg Versteeg, van Swaaij van Swaaij (1988c)
Solubility and Diffusivity of Acid Gases (CO 2 , N 2 O) in Aqueous Alkanolamine SolutionsJ. Chem. Eng. Data, 32
N. Haimour, A. Bidarian, O. Sandall (1987)
Kinetics of the reaction between carbon dioxide and methyldiethanolamineChemical Engineering Science, 42
(1988)
1988b) reported kinetic data a t 293
T. Donaldson, Y. Nguyen (1980)
Carbon Dioxide Reaction Kinetics and Transport in Aqueous Amine MembranesIndustrial & Engineering Chemistry Fundamentals, 19
(1988)
1988b) suggested a so-called Brfnsted relationship between the second-order rate constant, k,, and the acid dissociation constant K
D. Barth, C. Tondre, J. Delpuech (1984)
Kinetics and mechanisms of the reactions of carbon dioxide with alkanolamines: a discussion concerning the cases of MDEA and DEAChemical Engineering Science, 39
(1987)
reported experimental data for the absorption
Jørgensen Jørgensen, Faurholt Faurholt (1954)
Reactions between Carbon Dioxide and Amine AlcoholsActa Chem. Scand., 8
M. Jensen, E. Jørgensen, C. Faurholt, N. Sörensen (1954)
Reactions between Carbon Dioxide and Amino Alcohols. I. Menoethanolamine and Diethanolamine.Acta Chemica Scandinavica, 8
R. Tomcej, F. Otto (1989)
Absorption of CO2 and N2O into aqueous solutions of methyldiethanolamineAiche Journal, 35
D. Barth, C. Tondre, G. Lappai, J. Delpuech (1981)
Kinetic study of carbon dioxide reaction with tertiary amines in aqueous solutionsThe Journal of Physical Chemistry, 85
R. Pohorecki, W. Moniuk (1988)
Kinetics of reaction between carbon dioxide and hydroxyl ions in aqueous electrolyte solutionsChemical Engineering Science, 43
The reaction of CO2 with TEA, DMMEA, and DEMEA has been studied at 293, 303, 318 and 333 K. All the kinetic experiments were carried out in a stirred cell reactor operated with a flat, smooth and horizontal gas‐liquid interface. A numerical method, which describes mass transfer accompanied by reversible chemical reactions, has been applied to infer rate constants from the experimental data. It is argued that the contribution of the CO2 reaction with OH− to the observed reaction rate may have been overstimated in most literature on tertiary amine kinetics as serious depletion of OH− toward the gas‐liquid interface usually occurs. For all the amines studied, the reaction order in amine was found to be about one for each temperature investigated. This is in good agreement with the base catalysis mechanism proposed by Donaldson and Nguyen (1980). All kinetic data could be summarized reasonably well in one Brønsted relationship.
Aiche Journal – Wiley
Published: Nov 1, 1990
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