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Preparation and characterization of nickel–cobalt alloy nanostructures array fabricated by electrodeposition

Preparation and characterization of nickel–cobalt alloy nanostructures array fabricated by... A series of Ni–Co alloy nanocones arrays were fabricated by means of electrodeposition method without using any template. The alloy nanocones crystallized in the face-centered cubic lattice structure and grew preferentially along <110> directions. The aspect ratio of the alloy cones was found to increase with increasing cobalt content. The chemical potential difference of the solid–liquid interface and the synergistic effect of twinning were proposed to explain this phenomenon. By adjusting the electrodeposition conditions, the morphology and size of the alloy nanocrystal can be modulated. The crystal modifier plays an important role in controlling the step distance and the morphology of the spiral growth layer. These Ni–Co alloy nanocones arrays are expected to have significant potential applications in the fields of catalysis and magnetic storage. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png CrystEngComm Royal Society of Chemistry

Preparation and characterization of nickel–cobalt alloy nanostructures array fabricated by electrodeposition

CrystEngComm , Volume 16 (30) – May 13, 2014

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Publisher
Royal Society of Chemistry
Copyright
This journal is © the Partner Organisations 2014
ISSN
1466-8033
eISSN
1466-8033
DOI
10.1039/c4ce00565a
Publisher site
See Article on Publisher Site

Abstract

A series of Ni–Co alloy nanocones arrays were fabricated by means of electrodeposition method without using any template. The alloy nanocones crystallized in the face-centered cubic lattice structure and grew preferentially along <110> directions. The aspect ratio of the alloy cones was found to increase with increasing cobalt content. The chemical potential difference of the solid–liquid interface and the synergistic effect of twinning were proposed to explain this phenomenon. By adjusting the electrodeposition conditions, the morphology and size of the alloy nanocrystal can be modulated. The crystal modifier plays an important role in controlling the step distance and the morphology of the spiral growth layer. These Ni–Co alloy nanocones arrays are expected to have significant potential applications in the fields of catalysis and magnetic storage.

Journal

CrystEngCommRoyal Society of Chemistry

Published: May 13, 2014

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