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Yuan-Jyh Lee, Jieh-Ming Huang, S. Kuo, Jiann-Shing Lu, F. Chang (2005)
Polyimide and polyhedral oligomeric silsesquioxane nanocomposites for low-dielectric applicationsPolymer, 46
Zengping Zhang, G. Liang, Jieliang Wang, Penggang Ren (2007)
Epoxy/POSS organic–inorganic hybrids: Viscoelastic, mechanical properties and micromorphologiesPolymer Composites, 28
H. Fong, S. Dickens, G. Flaim (2005)
Evaluation of dental restorative composites containing polyhedral oligomeric silsesquioxane methacrylate.Dental materials : official publication of the Academy of Dental Materials, 21 6
Yonghong Liu, Sixun Zheng, Kang-ming Nie (2005)
Epoxy nanocomposites with octa(propylglycidyl ether) polyhedral oligomeric silsesquioxanePolymer, 46
A. Krupička, M. Johansson, A. Hult (2003)
Use and interpretation of scratch tests on ductile polymer coatingsProgress in Organic Coatings, 46
G. Li, Lichang Wang, H. Toghiani, T. Daulton, K. Koyama, C. Pittman (2001)
Viscoelastic and Mechanical Properties of Epoxy/Multifunctional Polyhedral Oligomeric Silsesquioxane Nanocomposites and Epoxy/Ladderlike Polyphenylsilsesquioxane BlendsMacromolecules, 34
G. Kickelbick (2003)
Concepts for the incorporation of inorganic building blocks into organic polymers on a nanoscaleProgress in Polymer Science, 28
E. Amerio, P. Fabbri, G. Malucelli, M. Messori, M. Sangermano, R. Taurino (2008)
Scratch resistance of nano-silica reinforced acrylic coatingsProgress in Organic Coatings, 62
L. Mazzocchetti, M. Scandola, E. Amerio, G. Malucelli, C. Marano (2006)
Preparation and characterization of hybrid nanocomposites coated on LDPEMacromolecular Chemistry and Physics, 207
G. Malucelli, A. Priola, M. Sangermano, E. Amerio, E. Zini, E. Fabbri (2005)
Hybrid nanocomposites containing silica and PEO segments: preparation through dual-curing process and characterizationPolymer, 46
Ryo Tamaki, Yasuyuki Tanaka, M. Asuncion, Jiwon Choi, Richard Laine (2001)
Octa(aminophenyl)silsesquioxane as a nanoconstruction site.Journal of the American Chemical Society, 123 49
C. Sanchez, B. Julián, P. Belleville, M. Popall (2005)
Applications of hybrid organic–inorganic nanocompositesJournal of Materials Chemistry, 15
K. Nam, Taegyo Lee, B. Bae, M. Popall (2006)
Condensation reaction of 3-(methacryloxypropyl)-trimethoxysilane and diisobutylsilanediol in non-hydrolytic sol-gel processJournal of Sol-Gel Science and Technology, 39
C. Pittman, G. Li, Hanli Ni (2003)
Hybrid inorganic/organic crosslinked resins containing polyhedral oligomeric silsesquioxanesMacromolecular Symposia, 196
A. Strachota, P. Whelan, J. Kriz, J. Brus, M. Urbanová, M. Šlouf, L. Matějka (2007)
Formation of nanostructured epoxy networks containing polyhedral oligomeric silsesquioxane (POSS) blocksPolymer, 48
Jiangfeng Mu, Yonghong Liu, Sixun Zheng (2007)
Inorganic–organic interpenetrating polymer networks involving polyhedral oligomeric silsesquioxane and poly(ethylene oxide)Polymer, 48
J. Fouassier, J. Rabek (1993)
Radiation Curing in Polymer Science and Technology—Volume II
M. Ochi, R. Takahashi, A. Terauchi (2001)
Phase structure and mechanical and adhesion properties of epoxy/silica hybridsPolymer, 42
Hybrid nanocomposite coatings were prepared by the UV‐curing technique with a methacrylic oligomer and multifunctional methacrylic polyhedral oligomeric silsesquioxane blocks (POSS®). The results obtained from the polyhedral compounds were compared with those of a disordered framework obtained by the condensation of a silica precursor (MEMO). The inorganic domains generated during synthesis created constraints in movement of polymer segments, which reflected in an increase in Tg of the hybrid nanocomposite coatings. The films were transparent. The random structure obtained by the condensation of the MEMO showed a stronger effect on Tg than that observed by introducing POSS®. The effect of inorganic domains reflected on thermal stability, surface hardness and mechanical properties of the hybrid nano‐composite coatings.
Macromolecular Materials & Engineering – Wiley
Published: Jan 13, 2009
Keywords: ; ; ;
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