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Ruthven Ruthven (1972)
Diffusional Resistance of Molecular Sieve PelletsCan. J. Chem. Eng., 50
Ruthven Ruthven, Derrah Derrah, Loughlin Loughlin (1973)
Diffusion of Light Hydrocarbons in 5A ZeoliteCan. J. Chem., 51
Habgood Habgood, MacDonald MacDonald (1970)
Effects of Micropores on Peak Shape and Retention Volume in Gas‐Solid ChromatographyAnal. Chem., 42
Lee Lee, Ruthven Ruthven (1977)
An Experimental Method for the Determination of Macropore Diffusivities in Molecular Sieve PelletsInd. Eng. Chem. Fundamentals, 16
MacDonald MacDonald, Habgood Habgood (1972)
A Gas Chromatographic Method for Determining Internal Diffusivities in Zeolite CatalystsCan. J. Chem. Eng., 50
Stalkup Stalkup, Deans Deans (1963)
Perturbation Velocities in Gas‐Liquid Chromatographic Partition ColumnsAIChE J., 9
Sarma Sarma, Haynes Haynes (1974)
Application of Gas Chromatography to Measurements of Diffusion in ZeolitesAdv. Chem., 133
Roberts Roberts, York York (1967)
Adsorption of Normal Paraffins from Binary Liquid Solutions by 5A Molecular SieveInd. Eng. Chem. Process Design Develop., 6
Ruthven Ruthven, Doetsch Doetsch (1976)
Diffusion of SF 6 in 5A ZeoliteJ. Chem. Soc. Faraday Trans I, 72
Sargent Sargent, Whitford Whitford (1971)
Diffusion of CO 2 in 5A Molecular SieveAdv. Chem., 102
Haynes Haynes, Sarma Sarma (1973)
A Model for the Application of Gas Chromatography Measurements of Diffusion in Bidisperse Structure CatalystsAIChE J., 19
Ma Ma, Mancel Mancel (1973)
Diffusion of Hydrocarbons in Mordenites by Gas ChromatographyAdv. Chem., 121
Ruthven Ruthven, Loughlin Loughlin (1971)
Sorption and Diffusion of n‐Butane in Linde 5A Molecular SieveChem. Eng. Sci., 26
Eberly Eberly (1969)
Diffusion Studies in Zeolites and Related Solids by Chromatographic TechniquesInd. Eng. Chem. Fundamentals, 8
Ruthven Ruthven, Derrah Derrah (1975)
Diffusion of Monatomic and Diatomic Gases in 4A and 5A ZeolitesJ. Chem. Soc. Faraday Trans I, 71
Hashimoto Hashimoto, Smith Smith (1973)
Macropore Diffusion in Molecular Sieve Pellets by ChromatographyInd. Eng. Chem. Fundamentals, 12
The chromatographic method has been used to study the sorption and diffusion of methane, ethane, propane, and cyclopropane in 5A molecular sieve. Both the equilibrium isotherms and the time constants for zeolitic diffusion, obtained from the chromatographic peaks, agree well with the values obtained previously by the gravimetric method, thus confirming the validity of the experimental technique. The results obtained in several previously reported chromatographic studies are reviewed, and it is shown that the apparent discrepancies between chromatographic and gravimetric data arise mainly from differences in the way in which the micropore diffusivity is defined. The relative advantages and disadvantages of the gravimetric and chromatographic methods are briefly considered.
Aiche Journal – Wiley
Published: Nov 1, 1977
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