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C. Tedmon (1966)
The Effect of Oxide Volatilization on the Oxidation Kinetics of Cr and Fe‐Cr AlloysJournal of The Electrochemical Society, 113
C. Fujii, R. Meussner (1964)
The Mechanism of the High‐Temperature Oxidation of Iron‐Chromium Alloys in Water VaporJournal of The Electrochemical Society, 111
C. Stearns, F. Kohl, G. Fryburg (1974)
Oxidative vaporization kinetics of Cr2O3 in oxygen from 1000 to 1300 CJournal of The Electrochemical Society, 121
H. Graham, H. Davis (1971)
Oxidation/Vaporization Kinetics of Cr2O3Journal of the American Ceramic Society, 54
Shen Jia-nian, Zhou Longjiang, Li Tiefan (1997)
High-temperature oxidation of Fe-Cr alloys in wet oxygenOxidation of Metals, 48
B. Ebbinghaus (1993)
Thermodynamics of gas phase chromium species: The chromium oxides, the chromium oxyhydroxides, and volatility calculations in waste incineration processesCombustion and Flame, 93
The oxidation of type 304L stainless steel wasinvestigated at 873 K in the presence of O2and O2 + 10% H2O. Oxidation timevaried between 1 and 672 hr. The oxidized samples wereinvestigated by a number of surface-analytical techniques includinggrazing-angle XRD, SEM/EDX, auger spectroscopy, SIMS andXPS. Oxidation in dry oxygen results in the formation acorundum-type oxide (Me2O3) withadditional formation of spinel oxides after prolonged exposure. Theoxide layer contained mainly chromium, with smalleramounts of Fe and Mn. Oxidation in the presence of watervapor results in an oxide that contains more Fe and less Cr, the outer part of the oxide beingdepleted in Cr. In the presence of water vapor, a massloss is detected after prolonged exposure. We show thatthe mass loss is caused by chromium evaporation. The volatile species is suggested to beCrO2(OH)2.
Oxidation of Metals – Springer Journals
Published: Oct 14, 2004
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