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- Publisher
- Wiley
- Copyright
- Copyright © 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
- ISSN
- 1615-4150
- eISSN
- 1615-4169
- DOI
- 10.1002/adsc.200600371
- Publisher site
- See Article on Publisher Site
Abstract
The hydroxylation of benzene to phenol with hydrogen peroxide was investigated using different solvents and a series of catalysts, obtained by modification of titanium silicalite (TS‐1). The best results were obtained after post‐synthesis treatment of TS‐1 with NH4HF2 and H2O2. The new catalyst (TS‐1B), used in the presence of a particular co‐solvent (sulfolane) is able to protect the produced phenol from over‐oxidation and dramatically enhanced the selectivity of the reaction.
Journal
Advanced Synthesis & Catalysis – Wiley
Published: Apr 2, 2007