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Kinetics of Exchange Reactions

Kinetics of Exchange Reactions THE shape of the curve obtained by plotting the concentration of a reactant or product against the time can in general be used to yield information about the way the rate of the reaction depends on concentration, in particular about its order. In the case of isotopic exchange reactions this is not possible even in principle, supposing the isotopes to have identical chemical properties. This rather amusing result does not appear to have been placed on record hitherto. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Nature Springer Journals

Kinetics of Exchange Reactions

MCKAY, H. A. C.
Nature , Volume 142 (3605) – Dec 3, 1938
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Publisher
Springer Journals
Copyright
Copyright © 1938 by Nature Publishing Group
Subject
Science, Humanities and Social Sciences, multidisciplinary; Science, Humanities and Social Sciences, multidisciplinary; Science, multidisciplinary
ISSN
0028-0836
eISSN
1476-4687
DOI
10.1038/142997b0
Publisher site
See Article on Publisher Site

Abstract

THE shape of the curve obtained by plotting the concentration of a reactant or product against the time can in general be used to yield information about the way the rate of the reaction depends on concentration, in particular about its order. In the case of isotopic exchange reactions this is not possible even in principle, supposing the isotopes to have identical chemical properties. This rather amusing result does not appear to have been placed on record hitherto.

Journal

Nature – Springer Journals

Published: Dec 3, 1938

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