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Surface Coordination Chemistry: Corrosion Inhibition by Tetranuclear Cluster Formation of Iron with Salicylaldoxime

Surface Coordination Chemistry: Corrosion Inhibition by Tetranuclear Cluster Formation of Iron... A tetranuclear iron cluster is the principal component of the purple coatings produced by treating a mild steel surface with a salicylaldoxime corrosion inhibitor. This was shown by comparison of the spectroscopic data with those of the cluster ({Fe(salH)(HsalH)}4), which was obtained from FeCl3 and salicylaldoxime (H2salH) and has a distorted tetrahedral arrangement of FeIII atoms coordinated by terminal (1−) and bridging (2−) salicylaldoximate ligands (the central core of the cluster is depicted). http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Angewandte Chemie International Edition Wiley

Surface Coordination Chemistry: Corrosion Inhibition by Tetranuclear Cluster Formation of Iron with Salicylaldoxime

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Publisher
Wiley
Copyright
© 1999 WILEY‐VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany
ISSN
1433-7851
eISSN
1521-3773
DOI
10.1002/(SICI)1521-3773(19990419)38:8<1119::AID-ANIE1119>3.0.CO;2-4
pmid
25138515
Publisher site
See Article on Publisher Site

Abstract

A tetranuclear iron cluster is the principal component of the purple coatings produced by treating a mild steel surface with a salicylaldoxime corrosion inhibitor. This was shown by comparison of the spectroscopic data with those of the cluster ({Fe(salH)(HsalH)}4), which was obtained from FeCl3 and salicylaldoxime (H2salH) and has a distorted tetrahedral arrangement of FeIII atoms coordinated by terminal (1−) and bridging (2−) salicylaldoximate ligands (the central core of the cluster is depicted).

Journal

Angewandte Chemie International Edition – Wiley

Published: Apr 19, 1999

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