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References (50)
-
L. Gelato, E. Parthé (1987)
STRUCTURE TIDY– a computer program to standardize crystal structure dataJournal of Applied Crystallography, 20
-
A. Götze, H. Auer, R. Finger, T. Hansen, H. Kohlmann (2017)
A sapphire single-crystal cell for in situ neutron powder diffraction of solid-gas reactionsPhysica B: Condensed Matter
-
N. Ohba, M. Aoki, T. Noritake, K. Miwa, S. Towata (2005)
First-principles study of a hydrogen storage material CaSiPhysical Review B, 72
-
Germany (fax: (+49)7247-808-666; e-mail: crysdata(at)fizkarlsruhe(dot)de, on quoting the deposition numbers CSD-433794 (α-BaGeD0.09) -
Henry Auer, R. Schlegel, Oliver Oeckler, H. Kohlmann (2017)
Structural and Electronic Flexibility in Hydrides of Zintl Phases with Tetrel-Hydrogen and Tetrel-Tetrel Bonds.Angewandte Chemie, 56 40
-
H. Rietveld (1969)
A profile refinement method for nuclear and magnetic structuresJournal of Applied Crystallography, 2
-
(2010)
C: Lal -
H. Kohlmann, N. Kurtzemann, R. Weihrich, T. Hansen (2009)
In situ Neutron Powder Diffraction on Intermediate Hydrides of MgPd3 in a Novel Sapphire Gas Pressure CellZeitschrift für anorganische und allgemeine Chemie, 635
-
H. Rietveld (1967)
Line profiles of neutron powder-diffraction peaks for structure refinementActa Crystallographica, 22
-
Yunfeng Zhu, Wei Zhang, Zhibing Liu, Liquan Li (2010)
Hydrogen storage properties of the Zintl phase alloy SrAl2 doped with TiF3Journal of Alloys and Compounds, 492
-
N.A.A. Rusman, M. Dahari (2016)
A review on the current progress of metal hydrides material for solid-state hydrogen storage applicationsInternational Journal of Hydrogen Energy, 41
-
FullProf.2k, Version 5.30 -Mar2012-ILL JRC -
S. Orimo, Y. Nakamori, Jennifer Eliseo, A. Züttel, C. Jensen (2007)
Complex hydrides for hydrogen storage.Chemical reviews, 107 10
-
B. Sakintuna, F. Lamari-Darkrim, M. Hirscher (2007)
Metal hydride materials for solid hydrogen storage: a reviewInternational Journal of Hydrogen Energy, 32
-
Iryna Kurylyshyn, T. Fässler, A. Fischer, C. Hauf, G. Eickerling, Manuel Presnitz, W. Scherer (2014)
Probing the Zintl-Klemm concept: a combined experimental and theoretical charge density study of the Zintl phase CaSi.Angewandte Chemie, 53 11
-
Hui Wu, Wei Zhou, T. Udovic, J. Rush, T. Yildirim, M. Hartman, R. Bowman, J. Vajo (2007)
Neutron vibrational spectroscopy and first-principles calculations of the ternary hydrides Li4Si2H(D) and Li4Ge2H(D): Electronic structure and lattice dynamicsPhysical Review B, 76
-
Group-Subgroup realtions between space groups: a useful tool in crystal chemistry
MATCH: Commun. Math. Comput. Chem., 9
-
Strukturelle und elektronische Flexibilität in Hydriden von Zintl-Phasen mit Tetrel-Wasserstoff- und Tetrel-Tetrel-Bindung
Angew. Chem., 129
-
H. Wang, Huai-jun Lin, Weitong Cai, L. Ouyang, M. Zhu (2016)
Tuning kinetics and thermodynamics of hydrogen storage in light metal element based systems – A review of recent progressJournal of Alloys and Compounds, 658
-
(2015)
Reaction pathways to the Zintl phase hydrides CaSiH and MGeHx (M = Sr -
P. Wenderoth, H. Kohlmann (2013)
In situ neutron powder diffraction of the formation of SrGa2D2, and hydrogenation behavior of YbGa2 and EuGa2.Inorganic chemistry, 52 18
-
H. Auer, R. Guehne, M. Bertmer, S. Weber, P. Wenderoth, T. Hansen, J. Haase, H. Kohlmann (2017)
Hydrides of Alkaline Earth-Tetrel (AeTt) Zintl Phases: Covalent Tt-H Bonds from Silicon to Tin.Inorganic chemistry, 56 3
-
U. Häussermann, V. Kranak, K. Puhakainen (2010)
Hydrogenous Zintl Phases: Interstitial Versus Polyanionic HydridesChemInform, 139
-
Juan Rodriguez-Carvaj (1993)
Recent advances in magnetic structure determination neutron powder diffraction -
Q.-X. Xie, R. Nesper (2003)
Crystal structure of sodium strontium monogermanide, NaxSr1-xGe(x=0.14), 218
-
I. Jain, C. Lal, A. Jain (2010)
Hydrogen storage in Mg: A most promising materialInternational Journal of Hydrogen Energy, 35
-
V. Ting, P. Henry, H. Kohlmann, Chick Wilson, M. Weller (2010)
Structural isotope effects in metal hydrides and deuterides.Physical chemistry chemical physics : PCCP, 12 9
-
Elisabeth Bianco, Sheneve Butler, Shishi Jiang, O. Restrepo, W. Windl, J. Goldberger (2013)
Stability and exfoliation of germanane: a germanium graphane analogue.ACS nano, 7 5
-
VESTA -Visualisation for Electronic and STructural Analysis -
H. Auer, D. Wallacher, T. Hansen, H. Kohlmann (2017)
In Situ Hydrogenation of the Zintl Phase SrGe.Inorganic chemistry, 56 3
-
J. Chotard, W. Tang, P. Raybaud, R. Janot (2011)
Potassium silanide (KSiH3): a reversible hydrogen storage material.Chemistry, 17 44
-
F. Gingl, T. Vogt, E. Akiba (2000)
Trigonal SrAl2H2: the first Zintl phase hydrideJournal of Alloys and Compounds, 306
-
Daniel Bull, E. Weidner, Igor Shabalin, M. Telling, Catherine Jewell, Duncan Gregory, D. Ross (2010)
Pressure-dependent deuterium reaction pathways in the Li-N-D system.Physical chemistry chemical physics : PCCP, 12 9
-
H. Auer, H. Kohlmann (2017)
In situ Investigations on the Formation and Decomposition of KSiH3 and CsSiH3Zeitschrift für anorganische und allgemeine Chemie, 643
-
W. Harms, M. Wendorff, C. Röhr (2009)
Structure and bonding of ternary gallides CaGa1−x(Si/Sn/Al/In)x with the CrB type and related structuresJournal of Alloys and Compounds, 469
-
Hui-yue Wu, R. Michael, Hartman, T. Udovic, J. Rush, W. Zhou, Robert Jre, John Vajof (2007)
Structure of the novel ternary hydrides Li 4 Tt 2 D ( Tt = Si and Ge ) -
G. Behrendt, C. Reichert, H. Kohlmann (2016)
Hydrogenation Reaction Pathways in the Systems Li3N–H2, Li3N–Mg–H2, and Li3N–MgH2–H2 by in Situ X-ray Diffraction, in Situ Neutron Diffraction, and in Situ Thermal AnalysisJournal of Physical Chemistry C, 120
-
Hui Wu, M. Hartman, T. Udovic, J. Rush, Wei Zhou, R. Bowman, J. Vajo (2007)
Structure of the novel ternary hydrides Li4Tt2D (Tt=Si and Ge).Acta crystallographica. Section B, Structural science, 63 Pt 1
-
J. Zhang, S. Yan, H. Qu, X. Yu, P. Peng (2017)
Alkali metal silanides α-MSiH3: A family of complex hydrides for solid-state hydrogen storageInternational Journal of Hydrogen Energy, 42
-
T. Hansen, H. Kohlmann (2014)
Chemical Reactions followed by in situ Neutron Powder DiffractionZeitschrift für anorganische und allgemeine Chemie, 640
-
K. Momma, F. Izumi (2011)
VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology dataJournal of Applied Crystallography, 44
-
E. Cuervo-Reyes, E. Stalder, C. Mensing, Serhiy Budnyk, R. Nesper (2009)
Unexpected Magnetism in Alkaline Earth Mono-SilicidesarXiv: Other Condensed Matter
-
(2010)
Bärnighausen , Group - Subgroup realtions between space groups : a useful tool in crystal chemistry -
E. Reyes, R. Nesper (2012)
Electronic Structure and Properties of the Alkaline Earth MonosilicidesJournal of Physical Chemistry C, 116
-
Kasper Møller, B. Hansen, A. Dippel, J. Jørgensen, T. Jensen (2014)
Characterization of Gas-Solid Reactions using In Situ Powder X-ray DiffractionZeitschrift für anorganische und allgemeine Chemie, 640
-
T. Hansen, P. Henry, H. Fischer, J. Torregrossa, P. Convert (2008)
The D20 instrument at the ILL: a versatile high-intensity two-axis neutron diffractometerMeasurement Science and Technology, 19
-
M. Aoki, N. Ohba, T. Noritake, S. Towata (2004)
Reversible hydriding and dehydriding properties of CaSi: Potential of metal silicides for hydrogen storageApplied Physics Letters, 85
-
F. Stephens, Vincent Pons, R. Baker (2007)
Ammonia-borane: the hydrogen source par excellence?Dalton transactions, 25
-
D. Többens, S. Zander (2016)
KMC-2: an X-ray beamline with dedicated diffraction and XAS endstations at BESSY IIJournal of large-scale research facilities JLSRF, 2
-
David Bader, R. Pennington (2001)
ApplicationsThe International Journal of High Performance Computing Applications, 15
- Publisher
- de Gruyter
- Copyright
- ©2018 Walter de Gruyter GmbH, Berlin/Boston
- ISSN
- 2196-7105
- eISSN
- 2196-7105
- DOI
- 10.1515/zkri-2017-2142
- Publisher site
- See Article on Publisher Site
Abstract
AbstractHydrogenation products of the Zintl phases AeTt (Ae = alkaline earth; Tt = tetrel) exhibit hydride anions on interstitial sites as well as hydrogen covalently bound to Tt which leads to a reversible hydrogenation at mild conditions. In situ thermal analysis, synchrotron and neutron powder diffraction under hydrogen (deuterium for neutrons) pressure was applied to BaTt (Tt=Ge, Sn). BaTtHy (1<y<1.67, γ-phases) were formed at 5 MPa hydrogen pressure and elevated temperatures (400–450 K). Further heating (500–550 K) leads to a hydrogen release forming the new phases β-BaGeH0.5 (Pnma, a=1319.5(2) pm, b=421.46(2) pm, c=991.54(7) pm) and α-BaSnH0.19 (Cmcm, a=522.72(6) pm, b=1293.6(2) pm, c=463.97(6) pm). Upon cooling the hydrogen rich phases are reformed. Thermal decomposition of γ-BaGeHy under vacuum leads to β-BaGeH0.5 and α-BaGeH0.13 [Cmcm, a=503.09(3) pm, b=1221.5(2) pm, c=427.38(4) pm]. At 500 K the reversible reaction α-BaGeH0.23 (vacuum)⇄β-BaGeH0.5 (0.2 MPa deuterium pressure) is fast and was observed with 10 s time resolution by in situ neutron diffraction. The phases α-BaTtHy show a pronounced phase width (at least 0.09<y<0.36). β-BaGeH0.5 and the γ-phases appear to be line phases. The hydrogen poor (α- and β-) phases show a partial occupation of Ba4 tetrahedra by hydride anions leading to a partial oxidation of polyanions and shortening of Tt–Tt bonds.
Journal
Zeitschrift für Kristallographie - Crystalline Materials – de Gruyter
Published: Jun 27, 2018