Metal-mediated reactions towards the synthesis of a novel deaminolysed bisurea, dicarbamolyamine

Metal-mediated reactions towards the synthesis of a novel deaminolysed bisurea, dicarbamolyamine AbstractA new selective cobalt acetate tetrahydrate or cerium nitrate hexahydrate mediated cleavage of the C–N bond of a benzoyl isothiocyanate derivative to give (carbamoylamino)methanethioamide is presented. The cleavage of the C–N could not be achieved in the absence of thione. The novel silver-mediated conversion of a thione to the carbonyl was achieved on 1-((benzamido)formyl)urea and replicated on (carbamoylamino)methanethioamide to give the deaminolyzed bisurea (dicarbamolyamine). The compounds were characterized by IR, NMR, microanalysis and GC–MS. The single crystal X–ray diffraction studies of the crystal structures of compounds I, II, III and V is discussed. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Open Chemistry de Gruyter

Metal-mediated reactions towards the synthesis of a novel deaminolysed bisurea, dicarbamolyamine

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Publisher
De Gruyter Open
Copyright
© 2018 Felix Odame et al.
ISSN
2391-5420
eISSN
2391-5420
D.O.I.
10.1515/chem-2018-0058
Publisher site
See Article on Publisher Site

Abstract

AbstractA new selective cobalt acetate tetrahydrate or cerium nitrate hexahydrate mediated cleavage of the C–N bond of a benzoyl isothiocyanate derivative to give (carbamoylamino)methanethioamide is presented. The cleavage of the C–N could not be achieved in the absence of thione. The novel silver-mediated conversion of a thione to the carbonyl was achieved on 1-((benzamido)formyl)urea and replicated on (carbamoylamino)methanethioamide to give the deaminolyzed bisurea (dicarbamolyamine). The compounds were characterized by IR, NMR, microanalysis and GC–MS. The single crystal X–ray diffraction studies of the crystal structures of compounds I, II, III and V is discussed.

Journal

Open Chemistryde Gruyter

Published: Jun 1, 2018

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