Adsorption removal of methylene blue from aqueous solution on carbon-coated Fe3O4 microspheres functionalized with chloroacetic acid
Adsorption removal of methylene blue from aqueous solution on carbon-coated Fe3O4 microspheres...
Zhang, Zefei; Kim, Cholhwan; Fernandez, Carlos; Sundaram, Manickam Minakshi; Ramakrishnappa, Thippeswamy; Wang, Yuhong; Wang, Linshan; Sun, Ting; Hu, Xiaomin
2018-03-28 00:00:00
AbstractWe report the preparation and employability of carbon-coated Fe3O4 (Fe3O4/C) microspheres functionalized with chloroacetic acid (CAA) for the removal of methylene blue (MB) in aqueous solution. The prepared magnetic microspheres (Fe3O4/C-CAA) were characterized by the following techniques: X-ray diffraction, transmission electron microscopy, Fourier-transform infrared spectrometer, vibrating sample magnetometry, and Brunauer-Emmett-Teller. The characterization results showed that Fe3O4/C microspheres were modified by CAA without any phase change. Fe3O4/C-CAA microspheres have higher adsorption capacity for MB compared to Fe3O4/C microspheres. The Langmuir, Freundlich, and Temkin adsorption models were applied to describe the equilibrium isotherms, and the Langmuir adsorption model fitted well with the equilibrium data. The pseudo-first-order and pseudo-second-order kinetic models were used to describe the kinetics data. However, the pseudo-second-order kinetic model fitted better with the adsorption kinetics data.
http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.pngScience and Engineering of Composite Materialsde Gruyterhttp://www.deepdyve.com/lp/de-gruyter/adsorption-removal-of-methylene-blue-from-aqueous-solution-on-carbon-4nJxjDvcl0
Adsorption removal of methylene blue from aqueous solution on carbon-coated Fe3O4 microspheres functionalized with chloroacetic acid
AbstractWe report the preparation and employability of carbon-coated Fe3O4 (Fe3O4/C) microspheres functionalized with chloroacetic acid (CAA) for the removal of methylene blue (MB) in aqueous solution. The prepared magnetic microspheres (Fe3O4/C-CAA) were characterized by the following techniques: X-ray diffraction, transmission electron microscopy, Fourier-transform infrared spectrometer, vibrating sample magnetometry, and Brunauer-Emmett-Teller. The characterization results showed that Fe3O4/C microspheres were modified by CAA without any phase change. Fe3O4/C-CAA microspheres have higher adsorption capacity for MB compared to Fe3O4/C microspheres. The Langmuir, Freundlich, and Temkin adsorption models were applied to describe the equilibrium isotherms, and the Langmuir adsorption model fitted well with the equilibrium data. The pseudo-first-order and pseudo-second-order kinetic models were used to describe the kinetics data. However, the pseudo-second-order kinetic model fitted better with the adsorption kinetics data.
Journal
Science and Engineering of Composite Materials
– de Gruyter
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