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A new and facile method for the functionalization of a Merrifield resin with terpyridines: application as a heterogeneous catalyst for the synthesis of biaryls in environmentally friendly solvents

A new and facile method for the functionalization of a Merrifield resin with terpyridines:... Abstract A classical Merrifield resin was modified with pendant terpyridine heterocycles in order to develop a new material for heterogeneous catalysis. The protocol relies on the reaction of a pyrrolyl anion with chloromethyl groups present on the resin. The modified polymer was then reacted with a Pd salt to afford a catalyst that was tested in the Suzuki cross-coupling reaction in environmentally friendly solvents. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Green Processing and Synthesis de Gruyter

A new and facile method for the functionalization of a Merrifield resin with terpyridines: application as a heterogeneous catalyst for the synthesis of biaryls in environmentally friendly solvents

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Publisher
de Gruyter
Copyright
Copyright © 2016 by the
ISSN
2191-9542
eISSN
2191-9550
DOI
10.1515/gps-2015-0144
Publisher site
See Article on Publisher Site

Abstract

Abstract A classical Merrifield resin was modified with pendant terpyridine heterocycles in order to develop a new material for heterogeneous catalysis. The protocol relies on the reaction of a pyrrolyl anion with chloromethyl groups present on the resin. The modified polymer was then reacted with a Pd salt to afford a catalyst that was tested in the Suzuki cross-coupling reaction in environmentally friendly solvents.

Journal

Green Processing and Synthesisde Gruyter

Published: Jun 1, 2016

References