Thermoelectric and structural correlations in (Sr1−x−yCaxNdy)TiO3 perovskites

Thermoelectric and structural correlations in (Sr1−x−yCaxNdy)TiO3 perovskites Structural and thermoelectric properties are reported for a specially designed class of A-site substituted perovskite titanates, (Sr1−x−yCaxNdy)TiO3. Two series synthesized with various A-site Sr-rich or Ca-rich (Sr-poor) concentrations were investigated using high-resolution neutron powder diffraction as a function of temperature and Nd doping. Each series was designed to have a nominally constant tolerance factor at room temperature. We determine the room temperature structures as tetragonal I4/mcm and orthorhombic Pbnm for the Sr-rich and Ca-rich series, respectively. Three low-temperature orthorhombic structures, Pbnm, Ibmm, and Pbcm were also observed for the Sr-rich series, whereas the symmetry of the Ca-rich series remains unchanged throughout the full measured temperature range. Thermoelectric properties of (Sr1−x−yCaxNdy)TiO3 were investigated and correlated with the structural variables. We succeeded in achieving a relatively high figure of merit ZT=0.07 at ∼400K in the Sr-rich Sr0.76Ca0.16Nd0.08TiO3 composition which is comparable to that of the best n-type TE SrTi0.80Nb0.20O3 oxide material reported to date. For a fixed tolerance factor, the Nd doping enhances the carrier density and effective mass at the expense of the Seebeck coefficient. Thermal conductivity greatly reduces upon Nd doping in the Ca-rich series. With an enhanced Seebeck coefficient at elevated temperatures and reduced thermal conductivity, we predict that Sr0.76Ca0.16Nd0.08TiO3 and similar compositions have the potential to become some of the best materials in their class of thermoelectric oxides. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Physical Review B American Physical Society (APS)

Thermoelectric and structural correlations in (Sr1−x−yCaxNdy)TiO3 perovskites

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Thermoelectric and structural correlations in (Sr1−x−yCaxNdy)TiO3 perovskites

Abstract

Structural and thermoelectric properties are reported for a specially designed class of A-site substituted perovskite titanates, (Sr1−x−yCaxNdy)TiO3. Two series synthesized with various A-site Sr-rich or Ca-rich (Sr-poor) concentrations were investigated using high-resolution neutron powder diffraction as a function of temperature and Nd doping. Each series was designed to have a nominally constant tolerance factor at room temperature. We determine the room temperature structures as tetragonal I4/mcm and orthorhombic Pbnm for the Sr-rich and Ca-rich series, respectively. Three low-temperature orthorhombic structures, Pbnm, Ibmm, and Pbcm were also observed for the Sr-rich series, whereas the symmetry of the Ca-rich series remains unchanged throughout the full measured temperature range. Thermoelectric properties of (Sr1−x−yCaxNdy)TiO3 were investigated and correlated with the structural variables. We succeeded in achieving a relatively high figure of merit ZT=0.07 at ∼400K in the Sr-rich Sr0.76Ca0.16Nd0.08TiO3 composition which is comparable to that of the best n-type TE SrTi0.80Nb0.20O3 oxide material reported to date. For a fixed tolerance factor, the Nd doping enhances the carrier density and effective mass at the expense of the Seebeck coefficient. Thermal conductivity greatly reduces upon Nd doping in the Ca-rich series. With an enhanced Seebeck coefficient at elevated temperatures and reduced thermal conductivity, we predict that Sr0.76Ca0.16Nd0.08TiO3 and similar compositions have the potential to become some of the best materials in their class of thermoelectric oxides.
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Publisher
The American Physical Society
Copyright
Copyright © ©2017 American Physical Society
ISSN
1098-0121
eISSN
1550-235X
D.O.I.
10.1103/PhysRevB.96.064105
Publisher site
See Article on Publisher Site

Abstract

Structural and thermoelectric properties are reported for a specially designed class of A-site substituted perovskite titanates, (Sr1−x−yCaxNdy)TiO3. Two series synthesized with various A-site Sr-rich or Ca-rich (Sr-poor) concentrations were investigated using high-resolution neutron powder diffraction as a function of temperature and Nd doping. Each series was designed to have a nominally constant tolerance factor at room temperature. We determine the room temperature structures as tetragonal I4/mcm and orthorhombic Pbnm for the Sr-rich and Ca-rich series, respectively. Three low-temperature orthorhombic structures, Pbnm, Ibmm, and Pbcm were also observed for the Sr-rich series, whereas the symmetry of the Ca-rich series remains unchanged throughout the full measured temperature range. Thermoelectric properties of (Sr1−x−yCaxNdy)TiO3 were investigated and correlated with the structural variables. We succeeded in achieving a relatively high figure of merit ZT=0.07 at ∼400K in the Sr-rich Sr0.76Ca0.16Nd0.08TiO3 composition which is comparable to that of the best n-type TE SrTi0.80Nb0.20O3 oxide material reported to date. For a fixed tolerance factor, the Nd doping enhances the carrier density and effective mass at the expense of the Seebeck coefficient. Thermal conductivity greatly reduces upon Nd doping in the Ca-rich series. With an enhanced Seebeck coefficient at elevated temperatures and reduced thermal conductivity, we predict that Sr0.76Ca0.16Nd0.08TiO3 and similar compositions have the potential to become some of the best materials in their class of thermoelectric oxides.

Journal

Physical Review BAmerican Physical Society (APS)

Published: Aug 7, 2017

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