Energy Dependent Stereodynamics of the Ne(P32)+Ar Reaction

Energy Dependent Stereodynamics of the Ne(P32)+Ar Reaction The stereodynamics of the Ne(P23)+Ar Penning and associative ionization reactions have been studied using a crossed molecular beam apparatus. The experiment uses a curved magnetic hexapole to polarize the Ne(P23), which is then oriented with a shaped magnetic field in the region where it intersects with a beam of Ar(S1). The ratios of Penning to associative ionization were recorded over a range of collision energies from 320 to 500  cm-1 and the data were used to obtain Ω state dependent reactivities for the two reaction channels. These reactivities were found to compare favorably to those predicted in the theoretical work of Brumer et al. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Physical Review Letters American Physical Society (APS)

Energy Dependent Stereodynamics of the Ne(P32)+Ar Reaction

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Energy Dependent Stereodynamics of the Ne(P32)+Ar Reaction

Abstract

The stereodynamics of the Ne(P23)+Ar Penning and associative ionization reactions have been studied using a crossed molecular beam apparatus. The experiment uses a curved magnetic hexapole to polarize the Ne(P23), which is then oriented with a shaped magnetic field in the region where it intersects with a beam of Ar(S1). The ratios of Penning to associative ionization were recorded over a range of collision energies from 320 to 500  cm-1 and the data were used to obtain Ω state dependent reactivities for the two reaction channels. These reactivities were found to compare favorably to those predicted in the theoretical work of Brumer et al.
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Publisher
American Physical Society (APS)
Copyright
Copyright © © 2017 American Physical Society
ISSN
0031-9007
eISSN
1079-7114
D.O.I.
10.1103/PhysRevLett.119.053001
Publisher site
See Article on Publisher Site

Abstract

The stereodynamics of the Ne(P23)+Ar Penning and associative ionization reactions have been studied using a crossed molecular beam apparatus. The experiment uses a curved magnetic hexapole to polarize the Ne(P23), which is then oriented with a shaped magnetic field in the region where it intersects with a beam of Ar(S1). The ratios of Penning to associative ionization were recorded over a range of collision energies from 320 to 500  cm-1 and the data were used to obtain Ω state dependent reactivities for the two reaction channels. These reactivities were found to compare favorably to those predicted in the theoretical work of Brumer et al.

Journal

Physical Review LettersAmerican Physical Society (APS)

Published: Aug 4, 2017

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