Element-specific channels for the photoexcitation of V-doped TiO2 nanoparticles

Element-specific channels for the photoexcitation of V-doped TiO2 nanoparticles Incorporation of dopants in semiconductors is commonly used to modify the optical response and improve the efficiency of related devices. A physical understanding with elemental and local sensitivity of the electron excitation and trapping channels which follow photoexcitation is a prerequisite for knowledge-based materials design. By using high-resolution x-ray absorption methods we show that, in V-doped TiO2 nanoparticles, subband-gap visible light absorption is predominantly due to excitation of electrons from V ions to defective and long-lived Ti sites. We thus identify an element-specific photoexcitation channel. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Physical Review B American Physical Society (APS)

Element-specific channels for the photoexcitation of V-doped TiO2 nanoparticles

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Element-specific channels for the photoexcitation of V-doped TiO2 nanoparticles

Abstract

Incorporation of dopants in semiconductors is commonly used to modify the optical response and improve the efficiency of related devices. A physical understanding with elemental and local sensitivity of the electron excitation and trapping channels which follow photoexcitation is a prerequisite for knowledge-based materials design. By using high-resolution x-ray absorption methods we show that, in V-doped TiO2 nanoparticles, subband-gap visible light absorption is predominantly due to excitation of electrons from V ions to defective and long-lived Ti sites. We thus identify an element-specific photoexcitation channel.
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Publisher
The American Physical Society
Copyright
Copyright © Published by the American Physical Society
ISSN
1098-0121
eISSN
1550-235X
D.O.I.
10.1103/PhysRevB.96.045303
Publisher site
See Article on Publisher Site

Abstract

Incorporation of dopants in semiconductors is commonly used to modify the optical response and improve the efficiency of related devices. A physical understanding with elemental and local sensitivity of the electron excitation and trapping channels which follow photoexcitation is a prerequisite for knowledge-based materials design. By using high-resolution x-ray absorption methods we show that, in V-doped TiO2 nanoparticles, subband-gap visible light absorption is predominantly due to excitation of electrons from V ions to defective and long-lived Ti sites. We thus identify an element-specific photoexcitation channel.

Journal

Physical Review BAmerican Physical Society (APS)

Published: Jul 7, 2017

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