Complex Quasi-Two-Dimensional Crystalline Order Embedded in VO2 and Other Crystals

Complex Quasi-Two-Dimensional Crystalline Order Embedded in VO2 and Other Crystals Metal oxides such as VO2 undergo structural transitions to low-symmetry phases characterized by intricate crystalline order, accompanied by rich electronic behavior. We derive a minimal ionic Hamiltonian based on symmetry and local energetics which describes structural transitions involving all four observed phases, in the correct order. An exact analysis shows that complexity results from the symmetry-induced constraints of the parent phase, which forces ionic displacements to form multiple interpenetrating groups using low-dimensional pathways and distant neighbors. Displacements within each group exhibit independent, quasi-two-dimensional order, which is frustrated and fragile. This selective ordering mechanism is not restricted to VO2: it applies to other oxides that show similar complex order. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Physical Review Letters American Physical Society (APS)

Complex Quasi-Two-Dimensional Crystalline Order Embedded in VO2 and Other Crystals

Preview Only

Complex Quasi-Two-Dimensional Crystalline Order Embedded in VO2 and Other Crystals

Abstract

Metal oxides such as VO2 undergo structural transitions to low-symmetry phases characterized by intricate crystalline order, accompanied by rich electronic behavior. We derive a minimal ionic Hamiltonian based on symmetry and local energetics which describes structural transitions involving all four observed phases, in the correct order. An exact analysis shows that complexity results from the symmetry-induced constraints of the parent phase, which forces ionic displacements to form multiple interpenetrating groups using low-dimensional pathways and distant neighbors. Displacements within each group exhibit independent, quasi-two-dimensional order, which is frustrated and fragile. This selective ordering mechanism is not restricted to VO2: it applies to other oxides that show similar complex order.
Loading next page...
 
/lp/aps_physical/complex-quasi-two-dimensional-crystalline-order-embedded-in-vo2-and-12yJ6IwjEo
Publisher
The American Physical Society
Copyright
Copyright © © 2017 American Physical Society
ISSN
0031-9007
eISSN
1079-7114
D.O.I.
10.1103/PhysRevLett.119.045501
Publisher site
See Article on Publisher Site

Abstract

Metal oxides such as VO2 undergo structural transitions to low-symmetry phases characterized by intricate crystalline order, accompanied by rich electronic behavior. We derive a minimal ionic Hamiltonian based on symmetry and local energetics which describes structural transitions involving all four observed phases, in the correct order. An exact analysis shows that complexity results from the symmetry-induced constraints of the parent phase, which forces ionic displacements to form multiple interpenetrating groups using low-dimensional pathways and distant neighbors. Displacements within each group exhibit independent, quasi-two-dimensional order, which is frustrated and fragile. This selective ordering mechanism is not restricted to VO2: it applies to other oxides that show similar complex order.

Journal

Physical Review LettersAmerican Physical Society (APS)

Published: Jul 28, 2017

There are no references for this article.

Sorry, we don’t have permission to share this article on DeepDyve,
but here are related articles that you can start reading right now:

Explore the DeepDyve Library

Search

Query the DeepDyve database, plus search all of PubMed and Google Scholar seamlessly

Organize

Save any article or search result from DeepDyve, PubMed, and Google Scholar... all in one place.

Access

Get unlimited, online access to over 18 million full-text articles from more than 15,000 scientific journals.

Your journals are on DeepDyve

Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.

All the latest content is available, no embargo periods.

See the journals in your area

DeepDyve

Freelancer

DeepDyve

Pro

Price

FREE

$49/month
$360/year

Save searches from
Google Scholar,
PubMed

Create lists to
organize your research

Export lists, citations

Read DeepDyve articles

Abstract access only

Unlimited access to over
18 million full-text articles

Print

20 pages / month

PDF Discount

20% off