Colloidal Spherocylinders at an Interface: Flipper Dynamics and Bilayer Formation

Colloidal Spherocylinders at an Interface: Flipper Dynamics and Bilayer Formation We study the response of a film of colloidal spherocylinders to compression by combining pressure-area isotherm measurements, microscopy, and computer simulations. We find that the behavior of the film depends strongly on the geometry of the particles. For a small aspect ratio, a uniform monolayer forms and then buckles. For a higher aspect ratio, particles flip to orient perpendicular to the interface; we show that flipping occurs in locations where the nematic ordering is low. Our experiments and simulations further demonstrate that the longest particles rearrange to self-assemble a colloidal bilayer, which is stable due to the unique geometry of spherocylinders at an interface. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Physical Review Letters American Physical Society (APS)

Colloidal Spherocylinders at an Interface: Flipper Dynamics and Bilayer Formation

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Colloidal Spherocylinders at an Interface: Flipper Dynamics and Bilayer Formation

Abstract

We study the response of a film of colloidal spherocylinders to compression by combining pressure-area isotherm measurements, microscopy, and computer simulations. We find that the behavior of the film depends strongly on the geometry of the particles. For a small aspect ratio, a uniform monolayer forms and then buckles. For a higher aspect ratio, particles flip to orient perpendicular to the interface; we show that flipping occurs in locations where the nematic ordering is low. Our experiments and simulations further demonstrate that the longest particles rearrange to self-assemble a colloidal bilayer, which is stable due to the unique geometry of spherocylinders at an interface.
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Publisher
American Physical Society (APS)
Copyright
Copyright © © 2017 American Physical Society
ISSN
0031-9007
eISSN
1079-7114
D.O.I.
10.1103/PhysRevLett.119.018001
Publisher site
See Article on Publisher Site

Abstract

We study the response of a film of colloidal spherocylinders to compression by combining pressure-area isotherm measurements, microscopy, and computer simulations. We find that the behavior of the film depends strongly on the geometry of the particles. For a small aspect ratio, a uniform monolayer forms and then buckles. For a higher aspect ratio, particles flip to orient perpendicular to the interface; we show that flipping occurs in locations where the nematic ordering is low. Our experiments and simulations further demonstrate that the longest particles rearrange to self-assemble a colloidal bilayer, which is stable due to the unique geometry of spherocylinders at an interface.

Journal

Physical Review LettersAmerican Physical Society (APS)

Published: Jul 7, 2017

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