Electroanalytical Ventures at Nanoscale Interfaces Between Immiscible Liquids

Electroanalytical Ventures at Nanoscale Interfaces Between Immiscible Liquids Ion transfer at the interface between immiscible electrolyte solutions offers many benefits to analytical chemistry, including the ability to detect nonredox active ionized analytes, to detect ions whose redox electrochemistry is accompanied by complications, and to separate ions based on electrocontrolled partition. Nanoscale miniaturization of such interfaces brings the benefits of enhanced mass transport, which in turn leads to improved analytical performance in areas such as sensitivity and limits of detection. This review discusses the development of such nanoscale interfaces between immiscible liquids and examines the analytical advances that have been made to date, including prospects for trace detection of ion concentrations. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Annual Review of Analytical Chemistry Annual Reviews

Electroanalytical Ventures at Nanoscale Interfaces Between Immiscible Liquids

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Publisher
Annual Reviews
Copyright
Copyright 2016 by Annual Reviews. All rights reserved
ISSN
1936-1327
eISSN
1936-1335
D.O.I.
10.1146/annurev-anchem-071015-041415
Publisher site
See Article on Publisher Site

Abstract

Ion transfer at the interface between immiscible electrolyte solutions offers many benefits to analytical chemistry, including the ability to detect nonredox active ionized analytes, to detect ions whose redox electrochemistry is accompanied by complications, and to separate ions based on electrocontrolled partition. Nanoscale miniaturization of such interfaces brings the benefits of enhanced mass transport, which in turn leads to improved analytical performance in areas such as sensitivity and limits of detection. This review discusses the development of such nanoscale interfaces between immiscible liquids and examines the analytical advances that have been made to date, including prospects for trace detection of ion concentrations.

Journal

Annual Review of Analytical ChemistryAnnual Reviews

Published: Jun 12, 2016

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