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HETEROGENEOUS CHEMISTRY OF CARBON AEROSOLS

HETEROGENEOUS CHEMISTRY OF CARBON AEROSOLS ▪ Abstract Atmospheric carbon particles originate from natural sources and from human activity. The processes that lead to their formation are varied and include fossil fuel combustion, biomass burning, and mechanical stress and wear of carbonaceous materials. In this review, we examine recent work on the structure and composition of carbon aerosol particles, and we describe how they react with the atmospherically abundant gases ozone, oxygen, sulfur dioxide, nitric acid, and nitrogen oxides. The study of carbon particles in the laboratory has shown that chemical reactivity depends strongly on the type of carbon used and on experimental conditions such as temperature and humidity. The variability in the results demonstrates the difficulty in extrapolating laboratory results to atmospheric conditions and in explaining the role of carbon particles in processes such as global warming and environmental chemical cycling. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Annual Review of Physical Chemistry Annual Reviews

HETEROGENEOUS CHEMISTRY OF CARBON AEROSOLS

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Publisher
Annual Reviews
Copyright
Copyright © 2006 by Annual Reviews. All rights reserved
ISSN
0066-426X
eISSN
1545-1593
DOI
10.1146/annurev.physchem.57.032905.104525
pmid
16599806
Publisher site
See Article on Publisher Site

Abstract

▪ Abstract Atmospheric carbon particles originate from natural sources and from human activity. The processes that lead to their formation are varied and include fossil fuel combustion, biomass burning, and mechanical stress and wear of carbonaceous materials. In this review, we examine recent work on the structure and composition of carbon aerosol particles, and we describe how they react with the atmospherically abundant gases ozone, oxygen, sulfur dioxide, nitric acid, and nitrogen oxides. The study of carbon particles in the laboratory has shown that chemical reactivity depends strongly on the type of carbon used and on experimental conditions such as temperature and humidity. The variability in the results demonstrates the difficulty in extrapolating laboratory results to atmospheric conditions and in explaining the role of carbon particles in processes such as global warming and environmental chemical cycling.

Journal

Annual Review of Physical ChemistryAnnual Reviews

Published: May 5, 2006

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