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The Cu K Absorption Edges of the Cuprous Halides

The Cu K Absorption Edges of the Cuprous Halides The x-ray K absorption edges of copper in crystalline CuCl, CuBr, and CuI have been measured with a double crystal spectrometer. Near the edge the experimental curves have been analyzed into component absorption lines. The most intense absorption maximum is due to excitation of the K electron into the 4 p level of the absorbing ion. However, the line structure is too complex to be completely explained by the unperturbed optical levels of Zn + or by any perturbation of these levels arising from crystalline fields. It is suggested that the excited electron is shared with neighboring ions even in the lowest states. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Physical Review American Physical Society (APS)

The Cu K Absorption Edges of the Cuprous Halides

Physical Review , Volume 67 (7-8) – Apr 1, 1945
6 pages

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Publisher
American Physical Society (APS)
Copyright
Copyright © 1945 The American Physical Society
ISSN
1536-6065
DOI
10.1103/PhysRev.67.217
Publisher site
See Article on Publisher Site

Abstract

The x-ray K absorption edges of copper in crystalline CuCl, CuBr, and CuI have been measured with a double crystal spectrometer. Near the edge the experimental curves have been analyzed into component absorption lines. The most intense absorption maximum is due to excitation of the K electron into the 4 p level of the absorbing ion. However, the line structure is too complex to be completely explained by the unperturbed optical levels of Zn + or by any perturbation of these levels arising from crystalline fields. It is suggested that the excited electron is shared with neighboring ions even in the lowest states.

Journal

Physical ReviewAmerican Physical Society (APS)

Published: Apr 1, 1945

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