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The x-ray K absorption edges of copper in crystalline CuCl, CuBr, and CuI have been measured with a double crystal spectrometer. Near the edge the experimental curves have been analyzed into component absorption lines. The most intense absorption maximum is due to excitation of the K electron into the 4 p level of the absorbing ion. However, the line structure is too complex to be completely explained by the unperturbed optical levels of Zn + or by any perturbation of these levels arising from crystalline fields. It is suggested that the excited electron is shared with neighboring ions even in the lowest states.
Physical Review – American Physical Society (APS)
Published: Apr 1, 1945
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