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The mixed-valent compound TmSe has been studied in its antiferromagnetic state ( T < T N =3.2) by resonant magnetic x-ray scattering. The (003) magnetic reflection shows two peaks as a function of incident energy corresponding to the L III absorption edges of its Tm 2 + and Tm 3 + configurations. This unambiguously establishes that long-range magnetic order is present for both valence states. An Anderson impurity model including multiplet and core-hole effects gives a good description of the data.
Physical Review B – American Physical Society (APS)
Published: Apr 1, 1993
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