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The syntheses and crystal structures of eleven new Hg( ii ) complexes with halogen (chloro, bromo, iodo) and 3,5-disubstituted pyridine ligands are reported. The eight chain polymers among ...
surface patterning, a unique phenomenon occurring in azobenzene‐containing polymers , is more efficient in halogen ‐bonded polymer –azobenzene complexes than in the analogous hydrogen‐bonded complexes ...
eight cases one-dimensional coordination polymers are found. In these chains cadmium( ii ) cations are linked in an edge-sharing fashion by halogen bridges in their pseudoequatorial plane, with terminal ...
and supramolecular chemistry, the complexes summarized here should give helpful information for further design and investigation of the elusive category of halogen -bonding supramolecular functional materials. halogen ...
RNCAuX complexes that we reported earlier associate as anti-parallel, one-dimensional aurophilic polymers with long Au⋯Au distances (∼3.6 Å) and exhibit orange–red phosphorescence, the analogous aurophilic ...
}) and the thioether-bridged polymer (SeBr 2 {MeS(CH 2 ) 3 SMe}), as the main products, together with halogenated ligand. The (SeX 2 (L) 2 ) and (SeX 2 (L–L)) complexes are all based upon distorted square planar ...
Temperature‐dependent Cu⋅⋅⋅Cu distances lead to the luminescence thermochromism of copper(I) coordination polymers with cubane‐like Cu4X4 cluster nodes (X= halogen ) according to a study on three ...
comprehensively examined. Based on the results, the structural parameter reveals that the Na atom binds strongly to N, P, and As atoms of the nanocages. Among the complexes , the smallest bond distance of 2.206 Å ...
with BF 3 led to polymerization of the phosphine and its adduct. While the complexes (Vi 3 P)BX 3 with X = Cl, Br and I are air-stable colorless crystalline solids, (Vi 3 P)BH 3 is a colorless, distillable ...
Pban whereas the iodide bridged complex was obtained in the supergroup Cmmm . The halogen substituted pyridines represent the most versatile ligands for the formation of coordination polymers —they can ...
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