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The preparation and characterisation of the Cr( i ) complexes (Cr(CO) 4 L) + (L = Ph 2 PN(R)PPh 2 , Ph 2 P(R)PPh 2 ), which are used as pre-catalysts for the selective oligomerization of ethylene ...
of the nuclear spin states composed of proton spin pairs using the molecular dynamics method and quantum chemistry simulations. We consider intramolecular and intermolecular dipolar, chemical shift anisotropy ...
sequence Arg 1 ‐Pro 2 ‐Pro 3 ‐Gly 4 ‐Phe 5 ‐Ser 6 ‐Pro 7 ‐Phe 8 ‐Arg 9 . It is involved in several physiological processes, including inflammation, vasodilation, pain, and symptoms associated with the common ...
) and solid-state (SS) NMR spectroscopies. In the following, we report 3 fundamental aspects of TDP-43 PrLD, namely (i) that the full TDP-43 PrLD (residues 267 to 414) form droplets at pH 4 and in the absence ...
]. The key player in the regulation of KSHV latency is the latency-associated nuclear antigen (LANA), which is detected in all KSHV infected cells [ 2 ], [ 3 ] and is required for the latent episomal replication ...
), or hypochlorous acid (HOCl, orange), using TlpD, CheW, and CheA (n = 3 ). Chemoeffectors were diluted in PBS buffer ( pH 7). (C) Functional assays are shown with 250 μM HOCl either added directly to the reconstituted ...
conditions were 1.0–1.2 mM RREIIB in 15 mM sodium phosphate, 25 mM NaCl, 0.1 mM EDTA, pH 6.4 with or without 3 mM MgCl2. Figure 2 . View largeDownload slide Off-resonance R1ρ NMR measurements in RREIIB ...
of amylose resin (NEB). Reactions were mixed on a nutator at 4 °C for 2 h, transferred to a micro- spin column (Bio-Rad), centrifuged at 1000 g for 1 min, washed with 100 μl binding buffer, eluted with 100 mM ...
to the free form of the peptide. To assign these resonances, we recorded 2D 1H-NOESY (150 ms NOESY mixing time) and 1H-TOCSY (70 ms DIPSI- 2 mixing) experiments (57–59) with 3 mM Rtt109419–433 peptide ...
)/ kcal/mol ΔTm_abs/°C ΔΔGabs (37°C)/kcal/mol AÇmfA 70 18 67 67 45 13 3 −5 CÇmfC 81 20 82 81 63 15 −1 −5 GÇmfG 78 18 76 76 56 14 2 − 4 UÇmfU 70 17 72 70 56 15 − 2 − 2 Unlabeled Çmf -labeled Sample Tm_abs/°C ...
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