TY - JOUR AU1 - Wilke, Manuel AU2 - Akhmetova, Irina AU3 - Rademann, Klaus AU4 - Emmerling, Franziska AB - The syntheses and crystal structures of two cerium(IV) phosphonates are presented. Cerium(IV) bis(phenylphosphonate) Ce(O3PC6H5)2 1 can be formed from precipitation and mechanochemical reaction, whereas cerium(IV) bis(carboxymethylphosphonate) monohydrate Ce(O3PCH2COOH)2 ยท H2O 2 is only accessible via ball milling. All reactions proceed very fast and are completed within a short time span. In situ measurements for the syntheses of 1 show that the product occurs within seconds or a few minutes, respectively. The structures were solved from powder X-ray diffraction data. TI - Mechanochemical synthesis of cerium(IV)-phosphonates JF - Journal of Materials Science DO - 10.1007/s10853-018-2507-x DA - 2018-06-04 UR - https://www.deepdyve.com/lp/springer-journals/mechanochemical-synthesis-of-cerium-iv-phosphonates-CJ63sUwgsC SP - 13733 EP - 13741 VL - 53 IS - 19 DP - DeepDyve ER -