TY - JOUR
AU - Krasnoborod’ko, D. A.
AB - The field of temperatures and conversions in the catalytic process of bulk polymerization of isoprene in apparatuses with a fixed bed of the reaction mixture (polymerization forms) has been studied theoretically and experimentally. It is shown that in an apparatus with a thin layer (3 mm high) the process temperature regime is close to isothermal. In an apparatuses with a higher layer (6 mm high), the approach to isothermal conditions and a corresponding rise in the apparatus productivity is achieved by a stepwise increase in the wall temperature at the time of the drop in the temperature curve of the polymerization. A computational and experimental method is proposed for determining the current conversion of the monomer from the measured values of the current temperature of the reaction mixture.
TI - Rising the Efficiency of the Isoprene Bulk Polymerization Apparatuses
JF - Russian Journal of Applied Chemistry
DO - 10.1134/S1070427220070125
DA - 2020-07-19
UR - https://www.deepdyve.com/lp/springer-journals/rising-the-efficiency-of-the-isoprene-bulk-polymerization-apparatuses-xogmFy0riQ
SP - 1027
EP - 1033
VL - 93
IS - 7
DP - DeepDyve
ER -