TY - JOUR
AU - Takeuchi, Seiji
AB - Optically active [1-(methoxycarbonyl)ethyl]cobaloximes coordinated with various axial bases were prepared and their photoracemization rates were measured in a solution state. It was found that although the electronic effect of the axial ligand was negligible on the rate of photochemical Co–C bond homolysis, the steric bulkines accelerated the rate remarkably. These results had a similar tendency to those observed in a previously reported reaction wtih 1-cyanoethyl cobaloximes, though the degree of rate enhancement due to the steric bulkiness of the axial ligand was extremely enlarged. The reason is also discussed.
TI - Preparation of Optically Active [1-(Methoxycarbonyl)ethyl]cobaloximes Coordinated with Various Axial Ligands and Their Photoracemization. Remarkable Steric Effect of Axial Ligand on the Co–C Bond Homolysis
JO - Bulletin of the Chemical Society of Japan
DO - 10.1246/bcsj.64.2656
DA - 2006-06-07
UR - https://www.deepdyve.com/lp/oxford-university-press/preparation-of-optically-active-1-methoxycarbonyl-ethyl-cobaloximes-xQTCwenVB7
SP - 2656
EP - 2660
VL - 64
IS - 9
DP - DeepDyve
ER -