TY - JOUR AU - Tao,, Zheng-Wu AB - Abstract The multiscale pore size and specific gas storage mechanism in organic-rich shale gas reservoirs make gas transport in such reservoirs complicated. Therefore, a model that fully incorporates all transport mechanisms and employs an accurate numerical method is urgently needed to simulate the gas production process. In this paper, a unified model of apparent permeability was first developed, which took into account multiple influential factors including slip flow, Knudsen diffusion (KD), surface diffusion, effects of the adsorbed layer, permeability stress sensitivity, and ad-/desorption phenomena. Subsequently, a comprehensive mathematical model, which included the model of apparent permeability, was derived to describe gas production behaviors. Thereafter, on the basis of unstructured perpendicular bisection grids and finite volume method, a fully implicit numerical simulator was developed using Matlab software. The validation and application of the new model were confirmed using a field case reported in the literature. Finally, the impacts of related influencing factors on gas production were analyzed. The results showed that KD resulted in a negligible impact on gas production in the proposed model. The smaller the pore size was, the more obvious the effects of the adsorbed layer on the well production rate would be. Permeability stress sensitivity had a slight effect on well cumulative production in shale gas reservoirs. Adsorbed gas made a major contribution to the later flow period of the well; the greater the adsorbed gas content, the greater the well production rate would be. This paper can improve the understanding of gas production in shale gas reservoirs for petroleum engineers. shale gas, apparent permeability, production rate, PEBI grid, fractured horizontal well Nomenclature Aij area of the interface between block i and block j, m2 C molarity of real gas, mol m–3 cμ molarity of adsorbed gas, mol m–3 Cg gas compressible coefficient, 1 Pa–1 dm molecular diameter of gas, m Di distances from the nodes of block i to the interface shared by blocks i and j, m Dj distances from the nodes of block j to the interface shared by blocks i and j, m Dk Knudsen diffusion coefficient, m2 s–1 Ds surface diffusion coefficient, m2 s–1 F total mass flux of gas for real gas, kg m–2 s–1 Fa total mass flux of adsorbed gas for real gas, kg m–2 s–1 Fb total mass flux of bulk gas for real gas, kg m–2 s–1 Fk mass flux by Knudsen diffusion for real gas, kg m–2 s–1 Fs mass flux of gas by surface diffusion for real gas, kg m–2 s–1 Fv mass flux by slip flow for real gas, kg m–2 s–1 Ga amount of adsorbed gas, m3 kg–1 i block i j block adjacent to block i Jik element of row i and column k in sparse Jacobian matrix J⃗ J⃗ sparse Jacobian matrix k permeability of shale matrix, m2 k0 permeability at zero effective stress, m2 kapp apparent permeability of shale gas reservoirs, m2 kv permeability of slip flow for real gas, m2 k′k gas flow conductance of Knudsen diffusion, m2 k′s gas flow conductance of surface diffusion, m2 k′v gas flow conductance of slip flow, m2 Kn Knudsen number for real gas in nanopores m associated with geometry of the conductive pore space M gas molecular mass, kg mol–1 Mi total mass density of the gas in block i, kg m–3 n current time level n + 1 next time level p pressure of shale gas reservoir, Pa p1 effective stress when pores are closed completely, Pa pc confining pressure, Pa pi pressure of block i, Pa pj pressure of block j, Pa pL Langmuir pressure, Pa pwf bottom hole pressure, Pa qg gas production or injection rate, m3 s–1 Q gas production/injection rate, kg s–1 r pore radius of shale matrix, m r0 initial pore radius of shale matrix, m rw well radius, m reff effective pore radius of shale matrix, m reff_stress effective pore radius of shale matrix considering geomechanicals effects, m R general gas constant, J K–1 mol–1 Sg initial gas saturation t elapsed time, s Tij transmissibility of the interface between block i and block j, kg Pa–1 s–1 tol calculating tolerance, Pa T reservoir temperature, K VL Langmuir volume in reservoir conditions, m3 kg–1 Vstd molar volume in standard conditions (273.15 K and 1.01325 MPa), m3 mol–1 Z gas deviation factor Δt time step, s ΔVi volume of block i, m3 α effective stress coefficient φ porosity of shale matrix φ0 initial porosity of shale matrix φeff effective porosity of shale matrix ρr shale density, m3 kg–1 σeff effective stress in shale matrix, Pa σeff_0 initial effective stress in shale matrix, Pa εv weighting factor of slip flow for real gas εk weighting factor of Knudsen diffusion for real gas θ gas coverage of real gas τ tortuosity of shale matrix λ mean free path of molecules for real gas, m μg gas viscosity, Pa s ρg gas density, kg m–3 1. Introduction With the dramatic decline in the production rate and reserves of conventional natural gas resources, shale gas has gradually provided an increasing contribution to the world’s natural gas supply in recent years. The development of shale gas reservoirs has attracted much interest and has played an important role in the energy industry of North America. However, in comparison to conventional gas reservoirs, shale gas reservoirs are characterized by multiple gas transport mechanisms during the development process. Hence, an accurate model for simulating and forecasting well production performance is urgently needed. Typical organic-rich shale gas reservoirs generally have ultralow porosity and permeability. Specifically, the porosity of shale formations is usually less than 10% and their permeability varies from the nanodarcy to the microdarcy range (Ghanizadeh et al2014). Nanoscale pores are dominant in shale gas reservoirs and pores with a pore radius of less than 10 nm account for 42% of the total pore space (Akkutlu and Fathi 2012). Organic pores usually have an even smaller radius (Adesida et al2011). In general, shale gas is stored as a bulk gas (free gas) in the matrix pore spaces and an adsorbed gas on the surface of organic material (Jenkins and Boyer 2008, Sun et al2013). Therefore, the specific pore sizes and forms of gas storage in shale gas reservoirs mean that gas transport in such reservoirs comprises a combination of several transport mechanisms such as viscous flow, slip flow (SF), Knudsen diffusion (KD), and surface diffusion (SD), as well as the adsorption/desorption of adsorbed gas with depressurization during production. In the past, a large number of papers have been published that concentrated on correcting the apparent permeability for gas transport in shale gas reservoirs. Beskok and Karniadakis (1999) developed a unified Hagen–Poiseuille-type equation, which has been extensively used to address the fundamental mechanisms of fluid transport in tight porous media, including continuum flow, SF, transition flow, and free molecular flow. Javadpour et al (2007) described gas flow in micropores in terms of Darcy flow and in nanopores in terms of KD, and a later paper (Javadpour 2009) presented an apparent model based on a linear superposition of SF and KD for gas flow in shale gas formations. Civan (2010) developed a permeability model for gas flow in tight porous media, which considered rarefaction effects and slippage effects on the basis of the Beskok–Karniadakis model. Civan et al (2011) presented an improved model to accurately describe the apparent permeability and diffusivity of shale gas. Azom and Javadpour (2012) incorporated SF and KD into a model of apparent permeability to simulate dual-continuum shale gas reservoirs. Xiong et al (2012) analyzed the impacts of non-Darcy flow effects and SD of an ideal gas on apparent permeability. Singh et al (2014) proposed that a combination of Darcy flow and Knudsen flow (without considering the Klinkenberg effect) can describe gas flow for a range of Knudsen flow conditions applicable to a shale gas system. Wu et al (2015a, 2015b, 2015c) combined viscous flow and KD based on weighting coefficients to study real gas transport in nanopores. Wang et al (2015a) discussed the influence of multilayer adsorption on SD and the contribution of SD to apparent permeability. Wu et al (2016) developed a comprehensive model of apparent permeability by coupling multiple mechanisms, including non-Darcy effects, real gas effects, geomechanical effects, and the effects of adsorption layers on gas transport. However, the impacts of geomechanical effects on effective pore radius and porosity were treated separately in this paper. Song et al (2016) developed a unified model of apparent permeability for both organic matrices and inorganic matrices by coupling multiple mechanisms separately. Furthermore, both gas adsorption/desorption phenomena (Sigal 2013, Yao et al2013a, 2013b, Negara and Sun 2016, Negara et al2016) and geomechanical effects (Yu and Sepehrnoori 2014, Cao et al2016, Song et al2016) can significantly lead to dynamic changes in the effective pore radius of the shale matrix during the depressurization process in shale gas reservoirs, which can further affect apparent permeability. Real gas effects can also distinctly affect gas transport at relatively high gas pressures (Wang et al2008, Ma et al2014, Zhao et al2015). Therefore, the influencing factors mentioned above must be considered in forecasts of numerical gas flow and productivity. None of the studies mentioned above comprehensively considers the impacts of factors that influence gas transport on the apparent permeability and production behaviors of shale gas, including gas transport mechanisms (viscous flow, SF, KD, and SD), adsorption/desorption phenomena of adsorbed gas, real gas effects, and geomechanical effects. Furthermore, the influence that these factors exert on the productivity performance of shale gas wells has rarely been quantitatively analyzed. In this paper, a more comprehensive model of apparent permeability that considers multiple influencing factors was first developed. In this model, the impacts of both the adsorbed layer and geomechanical effects on the effective pore radius, real gas effects, and different gas transport mechanisms are considered simultaneously in modeling the apparent permeability. Next, the governing mass balance equation was derived and a fully implicit numerical discretization scheme was presented based on the finite volume method with perpendicular bisection (PEBI) grids. Finally, sensitive analyses were performed to study the effects of the related influencing factors on the well production behaviors of multiple fractured horizontal wells in shale gas reservoirs. 2. Gas transport mechanisms in organic-rich shale gas reservoirs During shale gas exploitation, shale gas transport mechanisms mainly consist of viscous flow, SF, and KD for bulk gas and SD for adsorbed gas, as well as gas adsorption and desorption phenomena in the depressurization process (figure 1). Figure 1. View largeDownload slide Schematic diagram of gas transport in nanoscale shale gas reservoirs. Figure 1. View largeDownload slide Schematic diagram of gas transport in nanoscale shale gas reservoirs. 2.1. Effect of adsorption/desorption on effective pore radius Adsorbed gas on the surface of an organic matrix usually obeys a Langmuir isotherm. The relationship between the adsorbed gas volume and pressure for a real gas at a constant temperature is expressed as follows (Civan et al2013): Ga=VLp/ZpL+p/Z. 1 The coverage can be defined as the ratio of the adsorbed gas volume to the Langmuir volume. The coverage for a real gas can be expressed as follows: θ=p/ZpL+p/Z. 2 Hence, considering the pore space occupied by adsorbed gas molecules owing to adsorption/desorption phenomena, the effective pore radius of a shale matrix can be expressed as follows: reff=r0-θdm. 3 2.2. Influence of geomechanical effects on effective pore radius The influence of geomechanical effects in a shale matrix on permeability can be expressed as follows (Wasaki and Akkutlu 2015, Song et al2016, Cai et al2017): k=k01-σeffp1m3, 4 σeff=pc-αp. 5 The relationship between the permeability, porosity, pore radius, and tortuosity of a shale matrix can be expressed as follows: k=φr28τ. 6 When the effective stress varies from σeff_0 to σeff, the corresponding permeability varies from k0 to k. Simultaneously, the tortuosity is regarded as constant. By equations (4) and (6), the ratio between k and k0 can be expressed as follows: φr2φ0r02=1-σeffp1m31-σeff_0p1m3. 7 The porosity is directly proportional to the second power of the pore radius (Florence et al2007, Xiong et al2012, Cai et al2017): φeff=φ0reffr02. 8 Equation (7) can be simplified as follows: r4r04=1-σeffp1m31-σeff_0p1m3. 9 The effective pore radius considering geomechanical effects can be expressed as follows: reff_stress=r01-σeffp1m1-σeff_0p1m34. 10 Hence, considering the pore space occupied by adsorbed gas molecules and geomechanical effects, the effective pore radius of a shale matrix can be expressed as follows: reff=reff_stress-θdm. 11 2.3. Effect of gas properties Shale gas reservoirs are generally under relatively high-pressure conditions. The influence of the volume of gas molecules and gas intermolecular interactions cannot be neglected. Hence, gas under shale reservoir conditions cannot be regarded as an ideal gas. In this paper, a gas deviation factor is used as calculated in the literature (Dranchuk et al1973). The gas viscosity is as calculated in the literature (Lee et al1966). 2.4. Bulk gas transport The mean free path of molecules for a real gas can be expressed as follows (Civan 2010): λ=πZRT2Mμgp. 12 The Knudsen number for a real gas in nanopores can be expressed as follows: Kn=λreff. 13 2.4.1. Slip flow When the Knudsen number Kn is less than 0.1, the pore size of the shale matrix is larger than the mean free path of gas molecules. Gas transport is dominated by collision between gas molecules. This regime is referred to as SF. Thus, the mass flux of a real gas considering SF can be expressed as follows (Civan et al2011): Fv=-ρgkvμg∇p, 14 where kv=k0(1+α(Kn)Kn)1+4Kn1+Kn, 15 α(Kn)=12815π2tan-1(4Kn0.4). 16 By combining equations (6) and (11), equation (15) can be rearranged as follows: kv=φeffreff28τ(1+α(Kn)Kn)1+4Kn1+Kn. 17 2.4.2. Knudsen diffusion When the Knudsen number Kn is larger than 1, the pore size of the shale matrix is smaller than the mean free path of gas molecules. Gas transport is dominated by collisions between gas molecules and matrix pore walls. This regime is referred to as KD. Thus, the mass flux of a real gas considering diffusion can be expressed as follows (Javadpour 2009): Fk=-MDk∇c, 18 where Dk=φeffτ2reff38ZRTπM. 19 In terms of the molarity of a real gas, c can be expressed as follows: c=pZRT. 20 By substituting equation (20) into (18), we get Fk=-MDk∇pZRT=-DkρgCg∇p, 21 where Cg=1p-1Z∂Z∂p. 22 2.4.3. Total bulk gas flux Considering the typical conditions in shale reservoirs, the bulk gas transport mechanisms in shale matrix pores include continuum flow, SF, and transition flow (Civan et al2013). On the basis of two transport mechanisms, namely, SF and KD, respectively, Wu et al (2015b) sets the ratios of the frequency of gas intermolecular collisions and the frequency of collisions between gas molecules and pore walls to the total frequency of collisions as the weighting factors for SF and KD, respectively. Then, the total mass flux of the bulk gas for a real gas can be expressed as follows: Fb=εvFv+εkFk, 23 where εv=11+Kn, 24 εk=11+1/Kn. 25 2.5. Transport of adsorbed gas Under the initial conditions in shale gas reservoirs, gas is stored in nanopores in the form of bulk gas and free gas. During the depressurization process, adsorption/desorption phenomena accompany the production of gas. At the same time, the residual adsorbed gas on the surface of organic particles is transported via SD. 2.5.1. Surface diffusion The concentration gradient of the adsorbed gas is generally regarded as the driving force of SD (Zhao et al2016a). Thus, the mass flux of SD for a real gas can be expressed as follows (Wu et al2015a): Fs=-MDs∇cμ, 26 where cμ=ρrVstdGa. 27 By substituting equation (27) into (26), we get Fs=-MDsρrVLVstd∂θ∂p∇p, 28 where ∂θ∂p=p/(pLZ)(1+p/(pLZ))2Cg. 29 2.5.2. Total flux of adsorbed gas The total mass flux of adsorbed gas for a real gas can be expressed as follows: Fa=Fs. 30 2.6. Model of apparent permeability The total mass flux for a real gas can be expressed as the sum of the total mass flux of the bulk gas and the total mass flux of the adsorbed gas: F=Fb+Fa. 31 By substituting equations (23) and (30) into (31), we get F=-εvρgkvμg∇p+εk(DkρgCg∇p)+MDsρrVLVstd∂θ∂p∇p. 32 Equation (32) can be rearranged in the form of Darcy’s law: F=-ρgkappμg∇p, 33 where kapp is the apparent permeability, which can be expressed as follows: kapp=εvkv+εkDkμgCg+MDsμgρgρrVLVstd∂θ∂p. 34 According to equation (34), with considering weighting factors, the gas flow conductance of SF, KD, and SD can be expressed as follows: kv′=εvkv, 35 kk′=εkDkμgCg, 36 ks′=MDsμgρgρrVLVstd∂θ∂p. 37 2.7. Development of the continuity equation On the basis of the newly developed model of shale gas apparent permeability, which can accurately describe gas transport in shale pores by coupling multiple mechanisms, the continuity equation can be expressed as follows: ∇⋅ρgkappμg∇p+ρgQ=∂∂t(φeffρg)+∂∂t(Mcμ). 38 3. Numerical solution 3.1. Mesh generation The traditional method of modeling fractured shale gas reservoirs using regular Cartesian grids could have some disadvantages: (1) inflexibility in representing complex geologies; (2) inadequacy in capturing the elliptical flow geometries expected around the fracture tips; (3) problems caused by grid orientation effects (Olorode 2011). PEBI grids, which are also known as Voronoi grids, can overcome these disadvantages. Owing to the ultralow permeability of shale gas reservoirs, the multiple fractured horizontal well has been proved to be a common way to achieve commercial value in the process of shale gas extraction (Zhao et al2013, 2014, 2016b). In this paper, 2D PEBI grids are used to simulate the productivity behaviors of fractured shale gas reservoirs. Figure 2 shows PEBI grids of a fractured horizontal well with 28 fractures. Figure 3(a) represents a logarithmic radial refinement of the grid around the fracture tips and figure 3(b) represents a logarithmic refinement of the grid along the direction of the horizontal well. Figure 2. View largeDownload slide Plane view of the mesh used for application of the model. Figure 2. View largeDownload slide Plane view of the mesh used for application of the model. Figure 3. View largeDownload slide Plane view of the refinements of the grids. Figure 3. View largeDownload slide Plane view of the refinements of the grids. 3.2. Discretization of continuity equation Using the finite volume method with an implicit scheme, equation (38) and the supplemental equations can be numerically discretized as follows: -∑j(Tij(pi-pj))n+1+(ρgqg)in+1-(Min+1-Min)ΔViΔt=0 39Mi is the total mass density of the gas in block i, which can be expressed as follows: Mi=(φeffρg+Mcμ)i 40Tij is the transmissibility of the interface between block i and block j. On the basis of an upstream weighting scheme, Tij can be expressed as follows: Tij=AijDi+Djρgμgkappipi≥pjAijDi+Djρgμgkappjpi