TY - JOUR
AU1 - Seiller-Delevoye, B.
AU2 - Bruneau, C.
AU3 - Dixneuf, P.
AB - The ruthenium-catalyzed Markovnikov addition of acetic or benzoic acid to the triple bond of (E)-3-methylpent-2-en-4-yn-1-ol followed by acylation of the alcohol group in the diene formed under the action of low-toxic derivatives of carbonic and formic acids opens up a simple route to dienylic carbonates and formates. Activation of these esters by catalytic amounts of palladium(0) complexes under conditions of nucleophilic allylic substitution or decarboxylation affords functional dienes.
TI - Ruthenium- and palladium-catalyzed synthesis of polyfunctional 1,3-dienes
JF - Russian Chemical Bulletin
DO - 10.1007/BF02498160
DA - 2006-09-01
UR - https://www.deepdyve.com/lp/springer-journals/ruthenium-and-palladium-catalyzed-synthesis-of-polyfunctional-1-3-t9XTtMHTrt
SP - 913
EP - 917
VL - 47
IS - 5
DP - DeepDyve
ER -