TY - JOUR AU - Yokozawa, Tsutomu AB - Suzuki–Miyaura polycondensation of an excess of linearly extended, conjugated dibromo monomer with meta-phenylenediboronate and of an excess of the extensively conjugated, kinked dibromo monomer with para-phenylenediboronate in the presence of tBu3PPd(0) precatalyst, which has a strong propensity for intramolecular π-face transfer, afforded cyclic polymers with Mn 12 400–6400, although unstoichiometric polycondensation generally affords linear polymers. TI - Unstoichiometric Suzuki–Miyaura cyclic polymerization of extensively conjugated monomers JO - Polymer Chemistry DO - 10.1039/c8py01741g DA - 2019-03-05 UR - https://www.deepdyve.com/lp/royal-society-of-chemistry/unstoichiometric-suzuki-miyaura-cyclic-polymerization-of-extensively-t0XJOXKMbC SP - 1182 EP - 1185 VL - 10 IS - 10 DP - DeepDyve ER -