TY - JOUR
AU - Nakato, Yoshinori
AB - November, 1965] SHORT COMMUNICATIONS 2021 The Photo-Ionization of N, N, N', N'-Tetramethyl-p-phenylenediamine in Organic Matrices By Hiroshi TSUBOMURA, Naoto YAMAMOTO , Katsumi KIMURA, Tofu SATO Hikoichiro YAMADA, Masahiko KATO , Gentaro YAMAGUCHI and Yoshinori NAKATO (Received August 13, 1965) The photolytic formation of Wurster's blue The transient spectrum decayed exponentially cation from N, N, N', N'-tetramethyl-p-phenyl- with ƒÑe=82 ƒÊsec. With deaerated n-heptane enediamine (TMPD) in an organic rigid solutions, and also with aerated liquid paraffin matrix is well known after the pioneering solutions, no transient spectrum was obtained. research of Lewis and his collaborators .1) Not We have measured the fluorescence and much investigation has been made , however, phosphorescence spectra of TMPD at 77�‹K in Tnto the behavior of the electron ejected in the ethanol, EPA and MP. These spectra, together matrix, except for the interesting work reported with the absorption spectrum, may well be by Dolan and Albrecht.2) understood as those of the substituted ben- We have made flash-photolytic experiments zenes.3) In other words, no special band, such of TMPD, using two argon-filled flash lamps as the charge-transfer absorption band or the with a total discharge energy of 200-400 joules charge-transfer fluorescence band, appears at and the 
TI - The Photo-Ionization of N,N,N′,N′-Tetramethyl-p-phenylenediamine in Organic Matrices
JO - Bulletin of the Chemical Society of Japan
DO - 10.1246/bcsj.38.2021
DA - 2006-03-27
UR - https://www.deepdyve.com/lp/oxford-university-press/the-photo-ionization-of-n-n-n-n-tetramethyl-p-phenylenediamine-in-ixTldBqn2Y
SP - 2021
EP - 2021
VL - 38
IS - 11
DP - DeepDyve
ER -