TY - JOUR
AU - Sasada, Yoshio
AB - The structure of N-carboxy-γ-benzyl-l-glutamate anhydride has been determined by X-ray analysis. The crystal is orthorhombic; space group, P212121; Z=4 with a=7.766(1), b=27.470(4), and c=5.948(1) Å. The structure was deduced by the direct method and refined to a final R value of 0.057 for 1504 observed reflections by the block-diagonal least-squares method. The hydrogen bond is formed between the imino group and the carbonyl group of the side chain. The dimension of the five-membered ring is affected by the intermolecular hydrogen bond as compared with the crystal structures of the other N-carboxy anhydrides of α-amino acid.
TI - The Crystal and Molecular Structure of N-Carboxy-γ-benzyl-l-glutamate Anhydride
JF - Bulletin of the Chemical Society of Japan
DO - 10.1246/bcsj.51.2200
DA - 2006-04-19
UR - https://www.deepdyve.com/lp/oxford-university-press/the-crystal-and-molecular-structure-of-n-carboxy-benzyl-l-glutamate-fMB4VoA2VJ
SP - 2200
EP - 2204
VL - 51
IS - 8
DP - DeepDyve
ER -