TY - JOUR
AU - Kuromiya, Naoki
AB - The irradiation of methyl benzenesulfonate (1) in methanol undergoes a photolysis (Φdisapp=0.07±0.005) leading to benzene (5–34%), biphenyl (9–15%), and anisole (trace), in place of a photo-addition of methanol to give bicyclohexene derivatives. The rate of desulfonation of 1 is only slightly affected by triethylamine. Stern-Volmer quenching by piperylene occurs and the results suggest a significant singlet participation in this photolysis.
TI - Photolysis of Methyl Benzenesulfonate in Methanol
JO - Bulletin of the Chemical Society of Japan
DO - 10.1246/bcsj.48.3197
DA - 2006-03-27
UR - https://www.deepdyve.com/lp/oxford-university-press/photolysis-of-methyl-benzenesulfonate-in-methanol-e717w6EFZB
SP - 3197
EP - 3199
VL - 48
IS - 11
DP - DeepDyve
ER -