TY - JOUR
AU - Rieger, Bernhard
AB - The late transition metal catalysts for homo- and copolymerizations of olefins expand the polymer properties and the usable monomer feedstock of early transition metal catalysts. A critical step for a polymerization is the activation of catalyst precursors and the generation of the actual active site. This perspective discusses possible activation protocols for two well-known catalyst systems, the α-diimine Ni or Pd olefin polymerization catalysts and the Pd catalysts for alkene/CO copolymerization. The general concept of catalyst activation is outlined and similarities as well as differences between single-component catalysts and in situ activated systems are highlighted.
TI - Activation of late transition metal catalysts for olefin polymerizations and olefin/CO copolymerizations
JF - Dalton Transactions
DO - 10.1039/b802913j
DA - 2008-08-21
UR - https://www.deepdyve.com/lp/royal-society-of-chemistry/activation-of-late-transition-metal-catalysts-for-olefin-e0gdf9o9Fg
SP - 4537
EP - 4548
VL - 
IS - 34
DP - DeepDyve
ER -