TY - JOUR
AU - Ding, Kuiling
AB - A rhodium‐catalyzed one‐pot hydroformylation of olefins with CO2 , hydrosilane, and H2 has been developed that affords the aldehydes in good chemoselectivities at low catalyst loading. Mechanistic studies indicate that the transformation is likely to proceed through a tandem sequence of poly(methylhydrosiloxane) (PMHS) mediated CO2 reduction to CO and a conventional rhodium‐catalyzed hydroformylation with CO/H2. The hydrosilylane‐mediated reduction of CO2 in preference to aldehydes was found to be crucial for the selective formation of aldehydes under the reaction conditions.
TI - Rhodium‐Complex‐Catalyzed Hydroformylation of Olefins with CO2 and Hydrosilane
JO - Angewandte Chemie
DO - 10.1002/ange.201608628
DA - 2017-01-02
UR - https://www.deepdyve.com/lp/wiley/rhodium-complex-catalyzed-hydroformylation-of-olefins-with-co2-and-cmgjRmASUC
SP - 316
EP - 319
VL - 129
IS - 1
DP - DeepDyve
ER -