TY - JOUR
AU - Nomoto, Shinya
AB - A new asymmetric transformation of amino acids was described. Thus, when N-salicylidene-d-alanyl-, d-phenylalanyl-, or d-phenylglycyl-l-isoleucinatocopper(II) was incubated at pH 8.5 and 80°C, the resulting mixture at equilibrium contained a complex of l-l-dipeptide in the contents of 63–76%. The epimerization of dipeptides is based on the enhanced activity of N-terminal amino acids through complex formation.
TI - ASYMMETRIC TRANSFORMATION OF AMINO ACIDS IN N-SALICYLIDENE AMINO ACYL-l-ISOLEUCINATOCOPPER(II)
JF - Chemistry Letters
DO - 10.1246/cl.1980.1271
DA - 2006-03-27
UR - https://www.deepdyve.com/lp/oxford-university-press/asymmetric-transformation-of-amino-acids-in-n-salicylidene-amino-acyl-cl0Awp481A
SP - 1271
EP - 1274
VL - 9
IS - 10
DP - DeepDyve
ER -