TY - JOUR
AU - Ageev, E.
AB - The major products of the reaction of 2-bromohexanoic acid with methyl thiocyanate in trifluoroacetic acid are S-methyl 2-bromohexanethioate (II) (55% yield), S-methyl 2,2,2-trifluoroethanethioate (IV) (31% yield), N-trifluoro-acetyltrifluoroacetamide (V) (11% yield), and N-trifluoroacetyl-S-methylthiol-carbamate (III) (29% yield). N-2-Bromohexanoyl-S-methylthiolcarbamate (I), N-2-bromohexanoyltrifluoroacetaraide (VI), 2-thiapropioamide(VII), and S-methyl hex-anethioate (VIII) are also formed in minor amounts.
TI - Trifluoroacetic acid in the synthesis of thiolcarbamates and s-methyl alkanethioates
JO - Russian Chemical Bulletin
DO - 10.1007/BF00959656
DA - 2004-12-23
UR - https://www.deepdyve.com/lp/springer-journals/trifluoroacetic-acid-in-the-synthesis-of-thiolcarbamates-and-s-methyl-bOSyg9pb85
SP - 178
EP - 180
VL - 40
IS - 1
DP - DeepDyve
ER -