TY - JOUR
AU - Miyano, Sotaro
AB - Aryl- and allylsilanes are carboxylated with CO2 with the aid of aluminum-based Lewis acids, to give aromatic and β,γ-unsaturated carboxylic acids in fair to good yields, respectively. Formation of the former is rationalized by an aromatic electrophilic substitution by CO2 activated by the Lewis acid, while the latter a nucleophilic addition of in situ-generated allylaluminum species to CO2.
TI - Lewis Acid-Mediated Carboxylation of Aryl- and Allylsilanes with Carbon Dioxide
JF - Chemistry Letters
DO - 10.1246/cl.2003.454
DA - 2003-04-23
UR - https://www.deepdyve.com/lp/oxford-university-press/lewis-acid-mediated-carboxylation-of-aryl-and-allylsilanes-with-carbon-bGH1HiCaAI
SP - 454
EP - 455
VL - 32
IS - 5
DP - DeepDyve
ER -