TY - JOUR
AU - Ivasenko, V. L.
AB - Abstract We have carried out a quantum chemical analysis of the electronic structure of the nitroprusside ion [Fe(CN)5NO]2− and also the transition complex [Fe(CN)5NO· NH3]2− arising in the course of the reaction of reduction of coordinated nitrogen oxide with a nucleophile (ammonia). We consider the characteristics of the redistribution of electron density in the nitroprusside accompanying the nucleophilic attack. We discuss the role of the central iron ion and the CN-ligands during nucleophilic reduction.
TI - Quantum chemical analysis of the process of reduction of nitrogen oxide by ammonia
JF - Theoretical and Experimental Chemistry
DO - 10.1007/BF00530432
DA - 1990-07-01
UR - https://www.deepdyve.com/lp/springer-journals/quantum-chemical-analysis-of-the-process-of-reduction-of-nitrogen-b0NJRTWRi1
SP - 401
EP - 407
VL - 25
IS - 4
DP - DeepDyve
ER -