TY - JOUR
AU - Kang, Yun Chan
AB - High‐temperature flame spray pyrolysis is employed for finding highly efficient nanomaterials for use in lithium‐ion batteries. CoOx‐FeOx nanopowders with various compositions are prepared by one‐pot high‐temperature flame spray pyrolysis. The Co and Fe components are uniformly distributed over the CoOx‐FeOx composite powders, irrespective of the Co/Fe mole ratio. The Co‐rich CoOx‐FeOx composite powders with Co/Fe mole ratios of 3:1 and 2:1 have mixed crystal structures with CoFe2O4 and Co3O4 phases. However, Co‐substituted magnetite composite powders prepared from spray solutions with Co and Fe components in mole ratios of 1:3, 1:2, and 1:1 have a single phase. Multicomponent CoOx‐FeOx powders with a Co/Fe mole ratio of 2:1 and a mixed crystal structure with Co3O4 and CoFe2O4 phases show high initial capacities and good cycling performance. The stable reversible discharge capacities of the composite powders with a Co/Fe mole ratio of 2:1 decrease from 1165 to 820 mA h g−1 as the current density is increased from 500 to 5000 mA g−1; however, the discharge capacity again increases to 1310 mA h g−1 as the current density is restored to 500 mA g−1.
TI - Flame Spray Pyrolysis for Finding Multicomponent Nanomaterials with Superior Electrochemical Properties in the CoOx‐FeOx System for Use in Lithium‐Ion Batteries
JF - Chemistry - An Asian Journal
DO - 10.1002/asia.201402508
DA - 2014-10-01
UR - https://www.deepdyve.com/lp/wiley/flame-spray-pyrolysis-for-finding-multicomponent-nanomaterials-with-aHosAJsrVc
SP - 2826
EP - 2830
VL - 9
IS - 10
DP - DeepDyve
ER -