TY - JOUR
AU - Oestreich, Martin
AB - Reduced to the basics: Activation of Lewis acidic Cl3SiH with chiral amide‐based Lewis bases allows for the stereocontrolled reduction of several types of β‐enamino esters (see scheme). By this, the new motif of α‐acetoxy β‐enamino esters is transformed into α‐hydroxy β‐amino acids, a transformation still unknown in transition metal‐catalyzed hydrogenation. PMP=4‐methoxyphenyl.
TI - A New Motif for Lewis Base Catalysis: Asymmetric Reduction of β‐Enamino Esters
JF - ChemCatChem
DO - 10.1002/cctc.201100210
DA - 2012-05-17
UR - https://www.deepdyve.com/lp/wiley/a-new-motif-for-lewis-base-catalysis-asymmetric-reduction-of-enamino-Z2U7E9ereG
SP - 1527
EP - 1529
VL - 3
IS - 10
DP - DeepDyve
ER -