TY - JOUR AU - Yoshimura, Juji AB - Benzyl 2-acylamino-4-azido-2,4-dideoxypentopyranosides having α-d-ribo, β-l-ribo, α-d-lyxo, and β-l-lyxo configurations were derived from the corresponding α-d-xylo, β-l-xylo, α-d-arabino, and β-l-arabino isomers, respectively, by inversion of hydroxyl group on C-3. Displacement reaction of sulfonyloxy group with sodium acetate or benzoate in aqueous 2-methoxyethanol or anhydrous N,N-dimethylformamide, or oxidation-reduction method via ulose derivative was used properly according to the stereochemistry of the starting materials. TI - Aminosugars. XXXI. Preparation of Benzyl 2-Acylamino-4-azido-2,4-dideoxy-ribo- and -lyxopyranosides by Inversion of Hydroxyl Group on C-3 JF - Bulletin of the Chemical Society of Japan DO - 10.1246/bcsj.52.3051 DA - 2006-04-19 UR - https://www.deepdyve.com/lp/oxford-university-press/aminosugars-xxxi-preparation-of-benzyl-2-acylamino-4-azido-2-4-dideoxy-YNEMAl7FoB SP - 3051 EP - 3059 VL - 52 IS - 10 DP - DeepDyve ER -