TY - JOUR AU1 - Hu, Ziwei AU2 - Wang, Jian AU3 - Liang, Dongdong AU4 - Zhu, Qiang AB - A three‐component reaction involving isocyanides, o‐alkynyltrifluoroacetanilides, and amines for the efficient synthesis of 2‐substituted 1H‐indole‐3‐carboxamidines has been developed. The reaction proceeds through intramolecular aminopalladation of alkynes activated by isocyanide‐ligated palladium(II) species. Dioxygen acts as the sole oxidant to regenerate the active palladium(II) species. TI - Synthesis of 1 H ‐Indole‐3‐carboxamidines through a Palladium‐Catalyzed Three‐Component Reaction Involving Isocyanide Insertion as a Key Step JF - Advanced Synthesis & Catalysis DO - 10.1002/adsc.201300532 DA - 2013-11-11 UR - https://www.deepdyve.com/lp/wiley/synthesis-of-1-h-indole-3-carboxamidines-through-a-palladium-catalyzed-XcpWAZhdQv SP - 3290 EP - 3294 VL - 355 IS - 16 DP - DeepDyve ER -