TY - JOUR
AU - Jamison, Timothy F.
AB - A mild and facile method for preparing highly functionalized pyrrolo[1,2‐a]quinoxalines and other nitrogen‐rich heterocycles, each containing a quinoxaline core or an analogue thereof, has been developed. The novel method features a visible‐light‐induced decarboxylative radical coupling of ortho‐substituted arylisocyanides and radicals generated from phenyliodine(III) dicarboxylate reagents and exhibits excellent functional group compatibility. A wide range of quinoxaline heterocycles have been prepared. Finally, a telescoped preparation of these polycyclic compounds by integration of the in‐line isocyanide formation and photochemical cyclization has been established in a three‐step continuous‐flow system.
TI - Synthesis of Highly Functionalized Polycyclic Quinoxaline Derivatives Using Visible‐Light Photoredox Catalysis
JF - Angewandte Chemie International Edition
DO - 10.1002/anie.201408522
DA - 2015-10-22
UR - https://www.deepdyve.com/lp/wiley/synthesis-of-highly-functionalized-polycyclic-quinoxaline-derivatives-T0SyINMJKc
SP - 14451
EP - 14455
VL - 53
IS - 52
DP - DeepDyve
ER -