TY - JOUR
AU1 - Janani, Halimeh
AU2 - Rezvani, Ali
AU3 - Grivani, Gholam
AU4 - Mirzaei, Ali
AB - The application of mixed metal catalysts containing Co and Ce obtained from two different source materials—[Co(H2O)4NO3Ce(dipic)2] and [Co2(CO)6(2-py COO)Ce(NO3)2(THF)3]—was studied. Complexes were synthesized, characterized, and utilized for the Fischer–Tropsch conversion of synthesis gas to aliphatic hydrocarbons. The impregnated dipicolinate catalyst was pre calcined at 350 °C, whereas the carbonyl catalyst was used without calcination. Characterizations of the catalysts were carried out using powder X-ray diffraction, scanning electron microscopy and Brunauer–Emmett–Teller analysis surface area measurement. The carbonyl-derived bimetallic system showed higher selectivity toward olefin products (19–25 %) than the dipicolinate-derived system (15–16 %). Furthermore, the methane level produced with the carbonyl system was lower (14 %) than that for the dipicolinate system (20 %).
TI - Fischer–Tropsch Synthesis of Hydrocarbons over New Co/Ce Bimetallic Catalysts Derived from Dipicolinate and Carbonyl Metal Complexes
JF - Journal of Inorganic and Organometallic Polymers and Materials
DO - 10.1007/s10904-015-0225-2
DA - 2015-04-26
UR - https://www.deepdyve.com/lp/springer-journals/fischer-tropsch-synthesis-of-hydrocarbons-over-new-co-ce-bimetallic-SvBvOZioL9
SP - 1169
EP - 1182
VL - 25
IS - 5
DP - DeepDyve
ER -