TY - JOUR
AU - Oguchi, Sh\={o}shichi
AB - Irradiation of S-alkyl 3-oxobutanethioate (1) in benzene or ethanol yielded the disulfide 2. Irradiation of S-alkyl α-bromothioacetate also gave the disulfide 2. The photochemical reaction of the 3-oxobutanethioate 1 involves the Norrish Type I reaction followed by rapid fragmentation of the radical ·CH2COSR to the thiyl radical 5.
TI - Photochemical Reaction of S-Alkyl 3-Oxobutanethioate
JO - Bulletin of the Chemical Society of Japan
DO - 10.1246/bcsj.56.1869
DA - 2006-06-27
UR - https://www.deepdyve.com/lp/oxford-university-press/photochemical-reaction-of-s-alkyl-3-oxobutanethioate-SHYPZMVkg2
SP - 1869
EP - 1870
VL - 56
IS - 6
DP - DeepDyve
ER -