TY - JOUR
AU1 - Aomi, Yuta
AU2 - Nishida, Masakazu
AU3 - Sawada, Hideo
AB - Fluoroalkyl end‐capped vinyltrimethoxysilane oligomer [RF‐(VM)n‐RF] reacted with boric acid to afford the corresponding fluorinated oligomeric silica/boric acid nanocomposite [RF‐(VMSiO2)n‐RF/B(OH)3] fine particles with mean diameter: 36–105 nm. The obtained RF‐(VMSiO2)n‐RF/B(OH)3 nanocomposites were applied to the encapsulation of low molecular weight organic compounds such as diphenylsilanediol, 1,1′‐bi‐2‐naphthol, 4,4′‐biphenol, bisphenol A, bisphenol F, bisphenol AF, biphenyl, dibenzyl, and pentaerythritol into these nanocomposite cores to provide the corresponding fluorinated oligomeric silica/boric acid nanocomposites—encapsulated these organic molecules. Interestingly, the obtained nanocomposites were found to exhibit no weight loss behavior corresponding to the contents of these guest molecules even after calcination at 800 °C, although these nanocomposites were isolated through no purification process. The RF‐(VMSiO2)n‐RF nanocomposites—encapsulated these organic guest molecules were prepared under similar conditions. However, it was demonstrated that these nanocomposites can provide the clear weight loss corresponding to the contents of these guest molecules in the nanocomposites after calcination at 800 °C. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016, 54, 3835–3845
TI - Preparation and thermal stability of fluoroalkyl end‐capped vinyltrimethoxysilane oligomeric silica/boric acid nanocomposites‐encapsulated a variety of low molecular weight organic compounds
JF - Journal of Polymer Science Part A Polymer Chemistry
DO - 10.1002/pola.28280
DA - 2017-03-15
UR - https://www.deepdyve.com/lp/wiley/preparation-and-thermal-stability-of-fluoroalkyl-end-capped-QzKFl8REcd
SP - 3835
EP - 3845
VL - 54
IS - 24
DP - DeepDyve
ER -