TY - JOUR AU - Kulov, N. N. AB - The possibility of the formation of practically nonvolatile molecular complexes between the components of mixture and the separating agent of various compositions has been shown using the benzene–heptane–N-methylpyrrolidone system as an example. When modeling the vapor–liquid phase equilibrium, as a rule, the real structure of the solution is not taken into account, assuming the monomolecular structure of the substances contained in the solution. This significantly affects the real values ​​of coefficients of relative volatility, leading to the appearance of concentration inversion. The values ​​of fractions of substances in a monomolecular form are experimentally determined. TI - Effect of Separating Agent in Extractive Distillation JF - Theoretical Foundations of Chemical Engineering DO - 10.1134/S0040579520010145 DA - 2020-01-01 UR - https://www.deepdyve.com/lp/springer-journals/effect-of-separating-agent-in-extractive-distillation-P0byebPvM2 SP - 172 EP - 177 VL - 54 IS - 1 DP - DeepDyve ER -