TY - JOUR
AU - Wei, Tongye
AB - Dendrite formation and ongoing side reactions on the zinc anode are critical issues that hinder the application of zinc-ion batteries. Herein, a fluorine-containing carbon coating is applied to the zinc anode surface via laser irradiation. This coating enhanced the regulation of Zn2+ diffusion and nucleation behavior on the anode surface, promoting stable (002)-textured Zn deposition and reduction in side reactions. The strongly coupled coating enabled highly stable and reversible zinc stripping/plating for over 721 hours in Zn/Zn symmetric batteries at 5 mA cm−2 and 2.5 mA h cm−2. Moreover, the assembled full battery retained 80% of its initial capacity after 5500 cycles at a current density of 1 A g−1. Thus, it was demonstrated that surface modification with fluorine-containing carbon can improve the stability and reversibility of Zn anodes, thus accelerating the commercialization of ZIBs.
TI - Laser-induced fluorine-containing coating on zinc anode surface for regulated Zn(002) deposition
JF - Materials Chemistry Frontiers
DO - 10.1039/d5qm00063g
DA - 2025-03-01
UR - https://www.deepdyve.com/lp/royal-society-of-chemistry/laser-induced-fluorine-containing-coating-on-zinc-anode-surface-for-MO9u2gQdpm
SP - 1383
EP - 1388
VL - 9
IS - 9
DP - DeepDyve
ER -